Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter20: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 1ALQ
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Question
Interestingly, reduction of the complex shown above mostly gives the
alcohol enantiomer shown below after workup.
a. Draw the other minor diastereomeric alcohol product.
b. Briefly explain the diastereoselectivity of the reduction – why is one
enantiomer heavily favored? Draw a structure or structures to support your
answer.
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