Which one of the following reactions will occur spontaneously at standard-state conditions and 25°C? A)Mg2+ + Ca → Mg + Ca²+ B)Au + 3K+ → Au³+ + 3K Show work. C) D) 2A1³+ + 3Fe → 2A1+ 3Fe²+ Cu + 2H+ → Cu²+ + H₂
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- Consider the following dissociation reaction of iodine at 1000k: I2(g) <=> 2 I (g) The following data is relevent: v(I2)= 214.36 cm-1 ; B(I2)=0.0373 cm-1 ; De(I2)= 1.5422 eV The ground state of the iodine atoms is 2P3/2 , which implies fourfold degeneracy. Calculate the equilibrium constant for the reaction.Can the Nernst equation be used at temperatures other than room temperature?4. Which of the following best describes the timescales of fluorescence and phosphorescence? (b) Tfluorphos (d) there is no general trend Tfluor > Tphos Tfluor Tphos In 1-2 sentences, explain your reasoning:
- (a) NBS, hv 1A Br (b) Mg/Et,0 -CH3 1B > 10 NBS, 1 eq. (c) - 1D + 1E + 1F heat Brzieроxide 1G Br2/H20 1H H,SO,, heat 11 (d) ноTheir relationship is ALWAYS spontaneous -ΔΗ +ΔΗ +AS -AS +AG -AGIs the electronic contribution to the reaction constant in the reaction of 1 nitrogen atom with 1 oxygen atom, is it zero or not? Briefly reason.
- The Weibull distribution is widely used in statistical problems relating to aging of solid insulating materials subjected to aging and stress. Use this distribution as a model for time (in hours) to failure of solid insulating specimens subjected to AC voltage. The values of the parameters depend on the voltage and temperature; suppose ? = 2.2 and ? = 220. (a) What is the probability that a specimen's lifetime is at most 250? Less than 250? More than 300? (Round your answers to five decimal places.) at most 250 less than 250more than 300 (b) What is the probability that a specimen's lifetime is between 100 and 250? (Round your answer to four decimal places.) (c) What value (in hr) is such that exactly 50% of all specimens have lifetimes exceeding that value? (Round your answer to three decimal places.) hrFor 14N2, ΔG values for the transitions v= 1 ← 0, 2 ← 0, and 3 ← 0 are, respectively, 2329.91, 4631.20, and 6903.69cm-1. Calculate ?̃ and xe. Assume ye to be zero.Nit For a certain process, at 313 K, AG = −22.5 kJ and AH = -7.00 kJ. the process is carried out reversibly, what is the amount of use work that can be performed? || Nº -49.5 kJ -15.5 kJ -22.5 kJ II MAVZ ALL -10-328/4/26-34kL 62111-1 Can DT Reactants time of Nitrog Energy released -7.00 kJ -29.5 kJ x100
- Given that the molar entropy of a gas is: (+) SN=Na = R + Rln SN=Na = R + Rln ((² *² + RT i) Show that the molar entropy of a monatomic ideal gas (ignore electronic energy for now) can be written as (P is pressure): 12 * π *m* h² d(ln(q))) dT * T KB 3/2 * R* T V Navog * P 3 +-R ii) Calculate the molar entropy of Xe(g) at 298.15 K and compare this to the literature value. iii) Show that the change in entropy due to expansion for an ideal, monatomic gas is the same when using either a partition function approach or a thermodynamic approach.Derivation Calculate the entropy of HBr at 298 K and 1.00 bar, given that the bond length is 1.41 Å and the masses of ¹H and 79Br are 1.008 amu and 78.92 amu, respectively. The vibrational wavenumber is 2649 cm-1. Step 1 of 7 Provide the equation needed to calculate the translational contribution to the total entropy. (Use the following as necessary: h, kB, m to represent the mass, P, π, and T.) (31) BT) = R In Strans (2μmk B¹ h³ KBT (2πmkBT) kBT P h³ P Step 2 of 7 Substitute numerical values into the equation from Step 1 to obtain a numerical calculation for the translational entropy contribution. XJ.K-1.mol-1 Strans =146.211 SubmitA¡H° = 86 kJ mol-1 ,A;S = – 140 JK-1 mol-1 , T = 299 K Express your answer as an integer.