Which of the below electrodes behaves like a resistor and is designed to dissipate any chargeimbalance?O a Non-polarizable electrodeOb Silver electrodeOc Copper electrodeOd. Polarizable electrodeEinthoven lawAO a None of theseO b. A complex in lead III is equal to the sum of the corresponding complexes in leads II and 1.OC A complex in lead I is equal to the sum of the corresponding complexes in leads II and III.Od. A complex in lead II is equal to the sum of the corresponding complexes in leads I and III.

Resistor - Passive, two terminal electrical component that implements electrical resistance as a…

Answered: Which of the below electrodes behaves…

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter21: Potentiometry

Section: Chapter Questions

Problem 21.26QAP

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An active (metal) electrode was found to lose mass as the oxidation-reduction reaction was allowed to proceed. Was the electrode part of the anode or cathode? Explain.
The cell Ag|AgCl(sat’d)||H+(a = x)|glass electrode has a potential of —0.2094 V when the solution in the right-hand compartment is a buffer of pH 4.006. The following potentials are obtained when the buffer is replaced with unknowns: (a) —0.2806 V and (b) —0.2132 V. Calculate the pH and the hydrogen ion activity of each unknown. (c) Assuming anuncertainty of 0.001 Vin the junction potential, what is the range of hydrogen ion activities withinwhich the true value might be expected to lie?
Halide ions can he deposited at a silver anode, the reaction being Ag(s) + X- AgX(s) +e- Suppose that a cell was formed by immersing a silver anode in an analyte solution that was 0.0250 M Cl-,Br-, and I -ions and connecting the half-cell to a saturated calomel cathode via a salt bridge. (a) Which halide would form first and at what potential? Is the cell galvanic or electrolytic? (b) Could I- and Br- be separated quantitatively? (Take 1.00 l0-5 M as the criterion for quantitative removal of an ion.) If a separation is feasible, what range of cell potential could he used? (c) Repeat part (b) for I- and Cl-. (d) Repeat part (b) for Br- and Cl-.
Galvanic cells harness spontaneous oxidationreduction reactions to produce work by producing a current. They do so by controlling the flow of electrons from the species oxidized to the species reduced. How is a galvanic cell designed? What is in the cathode compartment? The anode compartment? What purpose do electrodes serve? Which way do electrons always flow in the wire connecting the two electrodes in a galvanic cell? Why is it necessary to use a salt bridge or a porous disk in a galvanic cell? Which way do cations flow in the salt bridge? Which way do the anions flow? What is a cell potential and what is a volt?
Calculate the equilibrium constant for the following reactions using data from the standard reduction potential tables. (a) Cl2(g)+2Br-(aq)Br2(g)+2Cl-(aq) (b) Ni(s)+2Ag+(aq)2Ag(s)+Ni2+(aq) (c) I2(s)+Sn2+(aq)2I(aq)+Sn4+(aq)
Consider the following electrochemical cell: a. If silver metal is a product of the reaction, is the cell a galvanic cell or electrolytic cell? Label the cathode and anode, and describe the direction of the electron flow. b. If copper metal is a product of the reaction, is the cell a galvanic cell or electrolytic cell? Label the cathode and anode, and describe the direction of the electron flow. c. If the above cell is a galvanic cell, determine the standard cell potential. d. If the above cell is an electrolytic cell, determine the minimum external potential that must be applied to cause the reaction to occur.
The measurement of pH using a glass electrode obeys the Nernst equation. The typical response of a pH meter at 25 00C is given by the equation where contains the potential of the reference electrode and all other potentials that arise in the cell that are not related to the hydrogen ion concentration. Assume that = 0.250 V and that a. What is the uncertainty in the values of pH and [H+] if the uncertainty in the measured potential is 1 m V ( 0.001 V)? b. To what precision must the potential be measured for the uncertainty in pH to be 0.02 pH unit?

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Which of the below electrodes behaves like a resistor and is designed to dissipate any charge imbalance? O a Non-polarizable electrode Ob Silver electrode Oc Copper electrode Od. Polarizable electrode