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- P (H2O) = exp (2.781699)A chemist, during the course of an analysis, runs across a chemical composed of carbon, hydrogen, and oxygen in the proportion 1:2:1 and having a six-sided molecular shape. It is probably (a) a pentose, (b) an amino acid, (c) a fatty acid, (d) a monosaccharide, (e) a nucleic acid.(NH4)2Ce(NO3)6 ? MeO
- a) the foul odor of rancid butter is due largely to butanoic acid, a compound contaning oxygen, hyrdrogen and carbon. Combustion analysis of a 4.30g sample of butyric acid produced 8.59g CO2 and 3.52 g H2O. Determine the empircal formula for butyric acid. b) a colourless liquid has a composition of 84.1% carbon and 15.9% hydorgen by mass. Determine the empirical formula. Also, assuming the molar mass of this compound is 114.2 g/mol, determine the molecular formula of this compound.The arrangement of atoms in several biologically important molecules is given here. Complete the Lewis structures of these molecules by adding multiple bonds and lone pairs. Do not add any more atoms. (a) the amino acid serine: 車 0-H H-C-H H Н—N—с—с—о—н H (b) нон H-N-C-N-H (c) pyruvic acid: ноо н—с—с—с—о—н H. (d) uracil: H (e) carbonic acid: H-0-C-0-H3. Use the symbols 6* and & to show the direction of the polarity of the indicated bond in H,C-OH. Use the symbois 6 and 6 to show the direction of the polarity of the indicated bond in each of the following compounds: (a) HO-H (b) F- Br (c) H,C- NH, (d) H,C-CI (e) HO - Br (1) H,C-Li (8) 1- CI (h) H,N - OH
- For each of the following covalent bonds: (a) use the symbols δ+ and δ- to indicate the direction of polarity (if any).(a) C-F; (b) N-Br; (c) B-C; (d) Si-H(b) Rank the following covalent bonds in order of increasing polarity. (i) C-H, O-H, N-H; (ii) C-N, C-O, B-O; (iii) C-P, C-S, C-NUse the following set of assumptions to estimate the CN bond length in fulminic acid: 1) only the two best structures contribute to the true structure 2) the best structure contributes 75%, 3) the CN single bond is 1.47 pm, the double is 1.32 pm and the triple is L.16 pm. Enter your answer with 2 significant figures as a number with no units. Structure I Structure II Structure III H-C=N=0 H-C=N-0 ŌI H-C-N=01 VFullsc 10:41 PM5. Show the structure of Teflon by drawing several repeating units. The monomer unit is tetrafluoroethylene, F2C=CF2. 6. Draw resonance structures for the following species: (a) CH2 (b) :0: (c) H. нн
- Is there an OH group present? Are there any C(sp2 )–H bonds? How about a carbon-carbon triple bond (alkyne) or a carbon-nitrogen triple bond (nitrile)? Is there a C=O?The organic molecules shown here are derivatives of benzene in which six-membered rings are “fused” at the edges of the hexagons. (a) Determine the empirical formula of benzene and of these three compounds. (b) Suppose you are given a sample of one of the compounds. Could combustion analysis be used to determine unambiguously which of the three it is? (c) Naphthalene, the active ingredient in mothballs, is a white solid. Write a balanced equation for the combustion of naphthalene to CO2(g) and H2O(g). (d) Using the Lewis structure for naphthalene and the average bond enthalpies in Table 8.4, estimate the heat of combustion of naphthalene in kJ/mol. (e) Would you expect naphthalene, anthracene, and tetracene to have multiple resonance structures? If so, draw the additional resonance structures for naphthalene. (f) Benzene, naphthalene, and anthracene are colorless, but tetracene is orange. What does this imply…Calculate the Enthalpy Change (ΔH) from average bond energies, which have been listed below in KJ/mol, for the following reaction and identify the nature of the reaction: CH3COOH + CH3OH → CH3COOCH3 + H2O [C‒H: 413; C‒C: 347; C=O: 745; C=C: 614; Cl‒Cl: 239, C‒O: 358; O‒H: 467]