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- 17-74 Glucose, C6H12O6, contains an aldehyde group but exists predominantly in the form of the cyclic hemiacetal shown here. We will discuss this cyclic form of glucose in Chapter 20. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. (a) Which carbon in glucose provides the —OH group and which provides the —CHO group? (b) Draw the alternative chair confirmations of D-glucose and state which of the two is the more stable.Identify the product, if any, that would form in each of the following reactions. 73) CH3 - CH2-CH2-OH [0] A) || CH3- CH2 - C- CH3 74) [0] B) CH 3 - CH 2 - CH -OH || CH3 CH3 - CH2 - CH Match the structural formula with the correct functional group. 75) CНз - СH2 -ОН A) alcohol 76) CH3 – CH2¤0 ICH3 B) thiol 77) CH3- CH2 - SH C) ether Select the correct name for the following. 78) CH3 - CH2 - CH2 - SH A) propanethiol 79) CH3 - CH2 - O - CH2 - CH3 B) diethyl ether 80) C) m-ethylphenol OH CH2CH3 D) 1-ethyl-3- hydroxycyclohexene E) propane sulfideThe reaction of ozone with 2-butene leads to -10 formation of aldehyde + ketone 0 aldehyde + alcohol 0 two molecules of carboxylic acid 0
- draw the chemical structure (condensed structure) of the following: i) 2-ethyl-2-methylpent-3-yn-1-ol ii) N-ethyl-N-propyl-2-methylbutanamide iii) (2R,3S)-2-bromopentan-1,3-diolWhat type of compound is the second product in the reaction shown below? CH O-C-(CH2)16CH3 CH-OH CH-O-C-(CH)16CH, +3 NaOH > CH-OH + CH O-C-(CH,)16CH, CHOH O ester O fatty acid O alcohol fatty acid saltDraw the structural formulas of the following compounds, name them according to IUPAC (1,2,3,4,5,6 examples), indicate the asymmetric carbon atoms. 5) γ-hydroxyvaleric acid 6) δ-hydroxyvaleric acid 7) 2-hydroxypentanoic acid 8) 3-hydroxy-2-methylbutanoic acid 9) 2,3- dihydroxybutanedioic acid (tartaric acid)
- An important step in one synthesis of carboxylic acids is the deprotonation of diethyl malonate and its alkyl-substituted derivative: Base CH;CH2O OCH,CH3 CH;CH,0 OCH2CH3 H2 Diethyl malonate Base CH;CH,0 °C `OCH,CH3 CH;CH,O OCH,CH3 R Alkyl substituted diethyl malonate NaOH can deprotonate diethyl malonate effectively, but NaOC(CH3)3 is typically used to deprotonate the alkyl-substituted derivative. Explain why.Which is the correct assignment of the names of the following substituted benzenes? OH CH3 HO, CH3 O 1 = phenol; 2 = m-cresol; 3 = toluene %3D O 1 = m-cresol; 2 = resorcinol; 3 = m-xylene %3D O 1 = anisole; 2 = catechol; 3 = m-xylene %3D %3D %3D O 1 = m-cresol; 2 = anisole; 3 = cumene %3DRefer to the following structures: K (V) -OH O I, II, III OI, VI O III, V OI, IV OVI DA NH₂ ✓ CH₂-CH-C²-OH Which of these structures are esters? ورے • CH₂ TD ~^^N-CH₂
- What is the systematic name of the product P of this chemical reaction? CH3-CH2-CH2-C-OH + NaOH + H20CH;CH2CH,CH,CH2B1 NH3 G + H + excessWrite down the common (not IUPAC) names of the organic molecules that would be released if this molecule were hydrolyzed: о CH2 O-C-(CH2)7-CH=CH-CH2-CH=CH-(CH2)4-CH3 о CH-O-C-(CH2)7-CH=CH-CH2-CH=CH-CH2-CH=CH-CH2-CH3 CH2 O-C-(CH2)4-CH=CH-CH2-CH=CH-CH2-CH=CH-(CH2)4-CH3 Separate each name with a comma. You will find useful information in the ALEKS Data resource.