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- Rank the following carbonyls according to their electrophilicity (1 = most) OEt O of O NEt₂ O CF3 Oa) MeLi (excess) ether b) H3O+ H Ph3PCHMe (1 equiv) -78C 1) cat. H2SO4 1 equiv HO OH remove H₂O 2a) NaBH4 b) H3O+ 3) H2SO4, H2O cat. H+ MeNH2 (1 equiv) remove H₂OW X Select reagent W and Y 1 HNO3 H₂SO4 2 CH3C1₂ AICI 3 3 Cl₂, FeCl3 ) 4 503, H₂SO4 NO₂ S0₂t
- Base treatment of the following , -unsaturated carbonyl compound yields an anion by removal of H+ from the carbon. Why are hydrogens on the g carbon atom acidic?Thioglycolic acid, HSCH2CO2H, a substance used in depilatory agents (hair removers) has pKa = 3.42. What is the percent dissociation of thioglycolic acid in a buffer solution at pH = 3.0?The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?
- Electrostatic potential maps of anisole and thioanisole are shown. Which do you think is the stronger acid, p-methoxybenzoic acid or p-(methylthio)benzoic acid? Explain.Explain why HCl reacts more rapidly with compound A than compound B. A H H₂C H CH H BThe O-H hydrogen in acetic acid is much more acidic than any of the C-H hydrogens. Explain. Acetic acid
- Provide the required information for the reaction scheme below: OH Compound B Compound C OH Compound A CHO CH2OH CHO CH2OH Compound E Compound DWhat is the correct statement that links acidity to anion stability? A = CH3 CH2 O H B = CH3 CH2 NH2Part B but-2-en-1-ol but-2-enoic acid, CH3CH=CH-COOH. 1 eq. NaOCI ТЕМРО 1 РСС NaOCI НОАС EtMgBr H3O+ H,CrO4 ether or PCC NaOCI HOAC H,CrO4 or PCC excess NaOCI ТЕМPО H,CrO4