utorial Problem for Weak Base and Strong Acid ou are given an Erlenmeyer flask containing 100.00 mL of 0.100 M B and a buret containing 0.100 M HCI. B" is a weak acid with a K, of 5.9 x 10-6. Calculate the pH of the solution (to 2 decimal laces) after titrating the following volumes of HCI: Vhat is the pH after 0.0 mL HCI is added? 40M t this point no strong acid has been added, so you need to solve a weak base pH problem. Vhat volume of HCI is added at the equivalence point (to 0.1 mL)? 49 Vhat is the pH at the equivalence point? 40D t this point no strong acid or weak base remains, so you need to solve a weak acid pH problem for the weak base's conjugate acid. mL Vhat is the pH after 50.0 ml HCI is added? 40 ou are in the buffer region here. You need to find the relative ratio of [B-1/[HB]. Make sure to convert K, into K, before using the Henderson-Hasselbalch equation. Vhat is the pH after 150.0 mL HCI is added? 49 ou are in a region where both the weak conjugate acid and strong acid are present, so you need to solve a strong acid pH problem.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
Section: Chapter Questions
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Tutorial Problem for Weak Base and Strong Acid
You are given an Erlenmeyer flask containing 100.00 mL of 0.100 M B¯ and a buret containing 0.100M HCI. B¯ is a weak acid with a K of 5.9 x 10 º. Calculate the pH of the solution (to 2 decimal
places) after titrating the following volumes of HCl:
What is the pH after 0.0 mL HCI is added? 4.0
At this point no strong acid has been added, so you need to solve a weak base pH problem.
What volume of HCI is added at the equivalence point (to 0.1 mL)? 49
mL
What is the pH at the equivalence point? 49.
At this point no strong acid or weak base remains, so you need to solve a weak acid pH problem for the weak base's conjugate acid.
What is the pH after 50.0 mL HCl is added? 49
You are in the buffer region here. You need to find the relative ratio of [B-]/[HB]. Make sure to convert K, into K, before using the Henderson-Hasselbalch equation.
a
What is the pH after 150.0 mL HCI is added? 4.0/
You are in a region where both the weak conjugate acid and strong acid are present, so you need to solve a strong acid pH problem.
Transcribed Image Text:Tutorial Problem for Weak Base and Strong Acid You are given an Erlenmeyer flask containing 100.00 mL of 0.100 M B¯ and a buret containing 0.100M HCI. B¯ is a weak acid with a K of 5.9 x 10 º. Calculate the pH of the solution (to 2 decimal places) after titrating the following volumes of HCl: What is the pH after 0.0 mL HCI is added? 4.0 At this point no strong acid has been added, so you need to solve a weak base pH problem. What volume of HCI is added at the equivalence point (to 0.1 mL)? 49 mL What is the pH at the equivalence point? 49. At this point no strong acid or weak base remains, so you need to solve a weak acid pH problem for the weak base's conjugate acid. What is the pH after 50.0 mL HCl is added? 49 You are in the buffer region here. You need to find the relative ratio of [B-]/[HB]. Make sure to convert K, into K, before using the Henderson-Hasselbalch equation. a What is the pH after 150.0 mL HCI is added? 4.0/ You are in a region where both the weak conjugate acid and strong acid are present, so you need to solve a strong acid pH problem.
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