Use the Acid-Base table to write net equations and determine the equilibrium constants for the acid-base reactions that occur when aqueous solutions of the following are mixed. (Use the lowest possible coefficients. Omit states-of-matter in your answer. Your reaction arrow may be either a right arrow (-->) or an equilibrium arrow (<=>), depending upon the value of Keq for the reaction.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter15: Solutions Of Acids And Bases
Section: Chapter Questions
Problem 15.30QE
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Use the Acid-Base table to write net equations and determine the equilibrium constants for the acid-base reactions that occur when aqueous solutions of the following are mixed. (Use the lowest possible coefficients. Omit states-of-matter in your answer. Your reaction arrow may be either a right arrow (-->) or an equilibrium arrow (<=>), depending upon the value of Keq for the reaction.

(d) KHSO4 and ammonia
(e) H₂S and KCIO
perchloric acid
hydrohalic acid
sulfuric acid
nitric acid
hydronium ion
Acid Name
iodic acid
oxalic acid
nitrous acid
lactic acid
formic acid
chemPad
sulfurous acid
hydrogen sulfate ion
phosphoric acid
hydrofluoric acid
XX→→
ammonia
hydroxide ion
hydrogen oxalate ion
hydrazoic acid
acetic acid
carbonic acid
hydrogen sulfite ion
hydrosulfuric acid
dihydrogen phosphate ion H₂PO₂¹-
hypochlorous acid
HCIO
ammonium ion
NH₂¹+
hydrocyanic acid
HCN
hydrogen carbonate ion
HCO,¹
HPO42-
hydrogen phosphate ion
hydrogen sulfide ion
water
chemPad
XoXº
HS¹-
H₂O
NH₂
OH-
ConjugateAcid
H₂SO4
HNO3
H₂o¹+
HIO3
H₂C₂O4
H₂SO3
HSO₂¹-
H₂PO4
HF
HNO₂
Hey yoy
HCHOI
HC₂0₂¹-
HN₂
HCIO4
>>1
HX (X= 1, Br, CI) >>1
>>1
HC2H3O2
Hyoy
HSO3¹-
H₂S
Help
Greek
<<10-14
6.2 x 10-8 7.21 HPO2-
3.5 x 10-8 7.46 CIO-
56K 10-10 925 NH
4.0 x 10-10 9.40 CN-
4.7 x 10-11 10.33 Co₂,²-
4.8 x 10-13 12.32 PO₂¹
1.3 x 10-13 12.89 $²
1.0 x 10-14 14.00 OH¹-
<<10-14
Greek
NH₂¹-
0²-
Help
K-407
>>1
1.0
K = 49✓
K₂
0.17
5.9 x 10-2
1.5 x 10-2
1.2 x 10-2
7.5 x 10-3
7.2 x 10-
4.0x 10-4
ammonia
pKa
0.00
0.77
HC₂04¹-
HSO₂¹-
SO₂²-
H₂PO₂¹-
F1-
NO₂¹-
C₂H₂O₂¹-
CHO2
4.19 C₂04²-
N₂1-
1.23
1.82
1.92
2.12
3.14
3.40
3.85
3.74
6.4 x 10-5
1.8 x 104
6.4 x 10-5
1.9 x 10-5
1.8 x 10-5
4.3 x 10-7
4.72
4.74
6.37
7.00
1.0 x 10-7
1.0 x 10-7 7.00 HS¹-
cyanide ion
<0
<0
<O
<0
amide ion
oxide ion
carbonate ion
Conjugate Base
CIO4¹-
hydrogen phosphate on
hypochlorite ion
phosphate ion
sulfide ion
hydroxide ion
HSO 1-
NO3¹-
H₂O
103¹-
C₂H5O₂¹-
HCO3¹-
so₂²-
Base Name
perchlorate ion
halide ion
hydrogen sulfate ion
nitrate ion
water
iodate ion
hydrogen oxalate ion
hydrogen sulfite ion
sulfate ion
dihydrogen phosphate ion
fluoride ion
nitrite ion
lactate ion
formate ion
oxalate ion
azide ion
acetate ion
hydrogen carbonate ion
sulfite ion
hydrogen sulfide ion
Transcribed Image Text:(d) KHSO4 and ammonia (e) H₂S and KCIO perchloric acid hydrohalic acid sulfuric acid nitric acid hydronium ion Acid Name iodic acid oxalic acid nitrous acid lactic acid formic acid chemPad sulfurous acid hydrogen sulfate ion phosphoric acid hydrofluoric acid XX→→ ammonia hydroxide ion hydrogen oxalate ion hydrazoic acid acetic acid carbonic acid hydrogen sulfite ion hydrosulfuric acid dihydrogen phosphate ion H₂PO₂¹- hypochlorous acid HCIO ammonium ion NH₂¹+ hydrocyanic acid HCN hydrogen carbonate ion HCO,¹ HPO42- hydrogen phosphate ion hydrogen sulfide ion water chemPad XoXº HS¹- H₂O NH₂ OH- ConjugateAcid H₂SO4 HNO3 H₂o¹+ HIO3 H₂C₂O4 H₂SO3 HSO₂¹- H₂PO4 HF HNO₂ Hey yoy HCHOI HC₂0₂¹- HN₂ HCIO4 >>1 HX (X= 1, Br, CI) >>1 >>1 HC2H3O2 Hyoy HSO3¹- H₂S Help Greek <<10-14 6.2 x 10-8 7.21 HPO2- 3.5 x 10-8 7.46 CIO- 56K 10-10 925 NH 4.0 x 10-10 9.40 CN- 4.7 x 10-11 10.33 Co₂,²- 4.8 x 10-13 12.32 PO₂¹ 1.3 x 10-13 12.89 $² 1.0 x 10-14 14.00 OH¹- <<10-14 Greek NH₂¹- 0²- Help K-407 >>1 1.0 K = 49✓ K₂ 0.17 5.9 x 10-2 1.5 x 10-2 1.2 x 10-2 7.5 x 10-3 7.2 x 10- 4.0x 10-4 ammonia pKa 0.00 0.77 HC₂04¹- HSO₂¹- SO₂²- H₂PO₂¹- F1- NO₂¹- C₂H₂O₂¹- CHO2 4.19 C₂04²- N₂1- 1.23 1.82 1.92 2.12 3.14 3.40 3.85 3.74 6.4 x 10-5 1.8 x 104 6.4 x 10-5 1.9 x 10-5 1.8 x 10-5 4.3 x 10-7 4.72 4.74 6.37 7.00 1.0 x 10-7 1.0 x 10-7 7.00 HS¹- cyanide ion <0 <0 <O <0 amide ion oxide ion carbonate ion Conjugate Base CIO4¹- hydrogen phosphate on hypochlorite ion phosphate ion sulfide ion hydroxide ion HSO 1- NO3¹- H₂O 103¹- C₂H5O₂¹- HCO3¹- so₂²- Base Name perchlorate ion halide ion hydrogen sulfate ion nitrate ion water iodate ion hydrogen oxalate ion hydrogen sulfite ion sulfate ion dihydrogen phosphate ion fluoride ion nitrite ion lactate ion formate ion oxalate ion azide ion acetate ion hydrogen carbonate ion sulfite ion hydrogen sulfide ion
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