Use the observation in the first column to answer the question in the second column. observation The enthalpy of vaporization of Substance C is bigger than that of Substance D. At 1 atm pressure, Substance A boils at 117. °C and Substance B boils at 82. °C. At -2 °C, Substance E has a vapor pressure of 109. torr and Substance F has a vapor pressure of 59. torr. question At any temperature where both substances are liquid, which has the higher vapor pressure? Substance C Substance D Neither, C and D have the same vapor pressure. O It's impossible to know without more information. Which has a higher enthalpy of vaporization? Substance A Substance B Neither, A and B have the same enthalpy of vaporization. It's impossible to know without more information. Which has a higher enthalpy of vaporization? Substance E Substance F Neither, E and F have the same enthalpy of vaporization. It's impossible to know without more information. Y 5

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter9: Liquids And Solids
Section: Chapter Questions
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Question
Use the observation in the first column to answer the question in the second column.
observation
The enthalpy of vaporization
of Substance C is bigger than
that of Substance D.
At 1 atm pressure,
Substance A boils at
117. °C and Substance B
boils at 82. °C.
At -2 °C, Substance E has
a vapor pressure of
109. torr and Substance F
has a vapor pressure of
59. torr.
question
At any temperature where both substances are liquid, which
has the higher vapor pressure?
Substance C
Substance D
Neither, C and D have the same vapor pressure.
It's impossible to know without more information.
Which has a higher enthalpy of vaporization?
Substance A
Substance B
Neither, A and B have the same enthalpy of vaporization.
It's impossible to know without more information.
Which has a higher enthalpy of vaporization?
Substance E
Substance F
Neither, E and F have the same enthalpy of vaporization.
It's impossible to know without more information.
X
S
Transcribed Image Text:Use the observation in the first column to answer the question in the second column. observation The enthalpy of vaporization of Substance C is bigger than that of Substance D. At 1 atm pressure, Substance A boils at 117. °C and Substance B boils at 82. °C. At -2 °C, Substance E has a vapor pressure of 109. torr and Substance F has a vapor pressure of 59. torr. question At any temperature where both substances are liquid, which has the higher vapor pressure? Substance C Substance D Neither, C and D have the same vapor pressure. It's impossible to know without more information. Which has a higher enthalpy of vaporization? Substance A Substance B Neither, A and B have the same enthalpy of vaporization. It's impossible to know without more information. Which has a higher enthalpy of vaporization? Substance E Substance F Neither, E and F have the same enthalpy of vaporization. It's impossible to know without more information. X S
Expert Solution
Step 1

We know, at thermodynamic temperature, the enthalpy of vaporization of a liquid is proportional to its boiling point. Which means higher the enthalpy of vaporization of a liquid higher is the boiling point of it. 

And we know, higher the vapor pressure of a liquid lower is its boiling point. 

According to this concept the answer of the questions are given below - 

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