us Lithium co Cording to the br Calculate th 3.17 L of r 3.1 Hydrob It takes Molarity 17) 15) A solution is created by dissolving 0.907 moles of HCI (a strong acid) into water, making 13.9 Liters of solution. Calculate the [H] and the pH of this solution: (5) 16) What is the [H] of an acid sample that has a pH of 4.02? (3) What is the pH of an aqueous 4.50 M KOH solution (a strong base)? 18) What is the [OH] of a bleach sample that registers 12.65 on a pH meter? -8-

us Lithium co Cording to the br Calculate th 3.17 L of r 3.1 Hydrob It takes Molarity 17) 15) A solution is created by dissolving 0.907 moles of HCI (a strong acid) into water, making 13.9 Liters of solution. Calculate the [H] and the pH of this solution: (5) 16) What is the [H] of an acid sample that has a pH of 4.02? (3) What is the pH of an aqueous 4.50 M KOH solution (a strong base)? 18) What is the [OH] of a bleach sample that registers 12.65 on a pH meter? -8-

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter15: Solutions Of Acids And Bases

Section: Chapter Questions

Problem 15.13QE: Why have chemists not tabulated the fraction ionized for different acids? Such a table would make...

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A student prepares 455 mL of a KOH solution, but neglects to write down the mass of KOH added. His TA suggests that he take the pH of the solution. The pH is 13.33. How many grams of KOH were added?
The weak base, CIO (hypochlorite ion), is used in the form of NaCIO as a disinfectant in swimming pools and water treatment plants. What are the concentrations of HCIO and OH and the pH of a 0.015 M solution of NaCIO?
A solution is made by dissolving 15.0 g sodium hydroxide in approximately 450 mL water. The solution becomes quite warm, but after it is allowed to return to room temperature, water is added to bring the volume to 500.0 mL of solution. (a) Calculate the pH and pOH in the final solution. (b) Why would we wait for it to return to room temperature? (c) If the mass of the water used to initially dissolve the sodium hydroxide were exactly 450 g and the temperature of the water increased by 8.865 C, how much heat was given off by the dissolution of 15.0 g of solute? Assume the specific heat of the solution is 4.184 J/g. K. What is the molar heat change for the dissolution of sodium hydroxide (known as the enthalpy of solution, Hsol)?
For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.
Two students were asked to determine the Kb of an unknown base. They were given a bottle with a solution in it. The bottle was labeled aqueous solution of a monoprotic strong acid. They were also given a pH meter, a buret, and an appropriate indicator. They reported the following data: volume of acid required for neutralization = 21.0 mL pH after 7.00 mL of strong acid added = 8.95 Use the students' data to determme the Kb of the unknown base.
Consider two weak acids, HA (MM=138g/mol)and HB (MM=72.0g/mol). A solution consisting of 11.0 g of HA in 745 mL has the same pH as a solution made up of 5.00 g of HB in 525 mL. Which of the two acids is stronger? Justify your answer by an appropriate calculation.
In a particular solution, acetic acid is 11% ionized at 25 C. Calculate the pH of the solution and the mass of acetic acid dissolved to yield 1.00L of solution.
A chilled carbonated beverage is opened and warmed to room temperature. Does the pH change and, if so, how does it change?
Codeine, C23H21NO3, is an alkaloid (Kb = 6 2 109) used as a painkiller and cough suppressant. A solution of codeine is acidified with hydrochloric acid to pH 4.50. What is the ratio of the concentration of the conjugate acid of codeine to that of the base codeine?
Novocaine, C13H21O2N2Cl, is the salt of the base procaine and hydrochloric acid. The ionization constant for procaine is 7106. 15 a solution of novocaine acidic or basic? What are [H3O+], [OH-], and pH of a 2.0% solution by mass of novocaine, assuming that the density of the solution is 1.0 g/mL.
What is the pH of a solution obtained by mixing 235 mL of NaOH with a pH of 11.57 and 316 mL of Sr(OH)2 with a pH of 12.09? Assume that volumes are additive.
For which of the following solutions must we consider the ionization of water when calculating the pH or pOH? (a) 3108M HNO3. (b) 0.10 g HCl in 1.0 L of solution. (c) 0.00080 g NaOH in 0.50 L of solution. (d) 1107M Ca(OH)2. (e) 0.0245 M KNO3