Try fitting these data using Freundlich Isotherm and obtain its constants

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
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The following data were obtained for the adsorption of a certain material (ORA) on activated
carbon at 25 C.
Activated carbon mass
Sample
number
[ORA) initial (M)
[ORA] at equilibrium
(M)
0.0044
(g)
1
1.0119
0.0096
2
1.0186
0.0289
0.0207
3
1.0360
0.0578
0.0446
4
1.0129
0.0867
0.0721
5
1.0393
0.1156
0.1002
6
1.0312
0.1445
0.1270
7
1.0198
0.1926
0.1742
8
1.0270
0.2407
0.2227
9
1.0252
0.2889
0.1108
1. Try fitting these data using Langmuir Isotherm and obtain K and monolayer of ORA molecules
per one gram
2. Try fitting these data using Freundlich Isotherm and obtain its constants
3. Which isotherm describe best the adsorption of ORA on activated carbon and why?
4. If a monolayer of N2 molecules is 0.03075 mole per one gram of activated carbon, and the
surface area on one N2 molecules is 0.162 nm², determine:
a. surface area per one gram of activated carbon
b. surface area of one ORA molecule
Transcribed Image Text:The following data were obtained for the adsorption of a certain material (ORA) on activated carbon at 25 C. Activated carbon mass Sample number [ORA) initial (M) [ORA] at equilibrium (M) 0.0044 (g) 1 1.0119 0.0096 2 1.0186 0.0289 0.0207 3 1.0360 0.0578 0.0446 4 1.0129 0.0867 0.0721 5 1.0393 0.1156 0.1002 6 1.0312 0.1445 0.1270 7 1.0198 0.1926 0.1742 8 1.0270 0.2407 0.2227 9 1.0252 0.2889 0.1108 1. Try fitting these data using Langmuir Isotherm and obtain K and monolayer of ORA molecules per one gram 2. Try fitting these data using Freundlich Isotherm and obtain its constants 3. Which isotherm describe best the adsorption of ORA on activated carbon and why? 4. If a monolayer of N2 molecules is 0.03075 mole per one gram of activated carbon, and the surface area on one N2 molecules is 0.162 nm², determine: a. surface area per one gram of activated carbon b. surface area of one ORA molecule
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