The standard free energy change for the reaction is given as: Cr,03 (s) + 3H2 (g) = 2Cr (s) + 3H,0 (g) AG° = 97,650 –28.6 T cals/mole A solid solution of metal M and Cr is being heated to 1223 °C at 1 atm pressure. Calculate the maximum partial pressure of water vapor in otherwise pure hydrogen that is permissible without oxidizing the Cr. Assume that Cr has a higher affinity for oxygen than metal M.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter17: Electrochemistry And Its Applications
Section: Chapter Questions
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The standard free energy change for the reaction is given as:
Cr,03 (s) + 3H2 (g) = 2Cr (s) + 3H20 (g)
AG° = 97,650 –- 28.6 T cals/mole
A solid solution of metal M and Cr is being heated to 1223 °C at 1 atm pressure. Calculate the
maximum partial pressure of water vapor in otherwise pure hydrogen that is permissible without
oxidizing the Cr. Assume that Cr has a higher affinity for oxygen than metal M.
Transcribed Image Text:The standard free energy change for the reaction is given as: Cr,03 (s) + 3H2 (g) = 2Cr (s) + 3H20 (g) AG° = 97,650 –- 28.6 T cals/mole A solid solution of metal M and Cr is being heated to 1223 °C at 1 atm pressure. Calculate the maximum partial pressure of water vapor in otherwise pure hydrogen that is permissible without oxidizing the Cr. Assume that Cr has a higher affinity for oxygen than metal M.
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