The production of cement results in significant GHG emissions. The emissions are caused by the decomposition of calcium carbonate (limestone) to calcium oxide (lime) and carbon dioxide. This process known as calcination, is carried out in kilns. Therefore, additional GHGs are emitted as a result of heating the kilns. A large cement manufacturer uses a mix of coal, natural gas, and biomass in its boiler. This mix produces the following amounts of GHGs per Million BTUs of energy: • 250 lbs CO2/MMBtu • 5 lbs CH4/MMBtu • 0.36 lbs N2O/MMBtu Process carbon emissions from the calcination process produce 925 lbs of carbon dioxide per metric ton of cement. In addition, the plant uses 1.7 Million BTUs of energy per metric ton of cement. If the plant produces 180,000 metric tons of cement annually, how many metric tons of CO2e does it emit?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
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The production of cement results in significant GHG emissions. The emissions are caused by the decomposition of calcium carbonate (limestone) to calcium oxide (lime) and carbon dioxide. This process known as calcination, is carried out in kilns. Therefore, additional GHGs are emitted as a result of heating the kilns. A large cement manufacturer uses a mix of coal, natural gas, and biomass in its boiler. This mix produces the following amounts of GHGs per Million BTUs of energy:

• 250 lbs CO2/MMBtu

• 5 lbs CH4/MMBtu

• 0.36 lbs N2O/MMBtu

Process carbon emissions from the calcination process produce 925 lbs of carbon dioxide per metric ton of cement. In addition, the plant uses 1.7 Million BTUs of energy per metric ton of cement. If the plant produces 180,000 metric tons of cement annually, how many metric tons of CO2e does it emit?

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