The primary process to currently make hydrogen is Steam Methane Reforming (SMR) of natural gas. This involves two reaction steps in the gas phase at high temperature & high pressure using solid catalysts. The final reactor effluent is usually separated using a PSA (Pressure Swing Adsorption) process to produce a very high-purity hydrogen gas stream & a "tail gas" containing residual methane, CO, & hydrogen (that can be used for the process's heating requirements). The table on the right shows the composition of 100 kmol/hr reactor effluent that must be purified. The separation considerations are: The reactor effluent is cooled & free water is separated from the gas. The composition of the remaining water in the dried gas is 0.25 mol%. Answer the following: ● Reactor Effluent ● Cooling & Water Separator The H2 Product stream is essentially pure hydrogen but only 90% of the hydrogen in the Cooled Syn Gas is recovered as product. The remaining hydrogen is recovered in the Tail Gas stream. Free Water Cooled Syll Gus Component H2 H2O CO2 CO C1 Total How much hydrogen is produced in H2 Product [in kmol/hr]? How much free water is produced after the initial cooling step [in kmol/hr]? What is the composition of the Tail Gas stream [in mol%]? PSA Tail Gas H₂ Product Effluent mol% 55.9 26.1 13.9 0.1 4.0 100.0

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
The primary process to currently make hydrogen is Steam
Methane Reforming (SMR) of natural gas. This involves two
reaction steps in the gas phase at high temperature & high
pressure using solid catalysts. The final reactor effluent is
usually separated using a PSA (Pressure Swing Adsorption)
process to produce a very high-purity hydrogen gas stream &
a "tail gas" containing residual methane, CO, & hydrogen
(that can be used for the process's heating requirements).
The table on the right shows the composition of 100 kmol/hr reactor
effluent that must be purified. The separation considerations are:
The reactor effluent is cooled & free water is separated from the
gas. The composition of the remaining water in the dried gas is 0.25
mol%.
●
Answer the following:
●
Effluct
Reactor Cooling &
Water
Separator
●
The H2 Product stream is essentially pure hydrogen but only 90%
of the hydrogen in the Cooled Syn Gas is recovered as product. The
remaining hydrogen is recovered in the Tail Gas stream.
Free
Water
Cooled
Syll Gus
H2
H2O
CO2
CO
C1
Total
PSA
How much hydrogen is produced in H2 Product [in kmol/hr]?
How much free water is produced after the initial cooling step [in kmol/hr]?
What is the composition of the Tail Gas stream [in mol%]?
Tail
Gas
Effluent
Component mol%
55.9
26.1
13.9
0.1
4.0
100.0
H₂
Product
Transcribed Image Text:The primary process to currently make hydrogen is Steam Methane Reforming (SMR) of natural gas. This involves two reaction steps in the gas phase at high temperature & high pressure using solid catalysts. The final reactor effluent is usually separated using a PSA (Pressure Swing Adsorption) process to produce a very high-purity hydrogen gas stream & a "tail gas" containing residual methane, CO, & hydrogen (that can be used for the process's heating requirements). The table on the right shows the composition of 100 kmol/hr reactor effluent that must be purified. The separation considerations are: The reactor effluent is cooled & free water is separated from the gas. The composition of the remaining water in the dried gas is 0.25 mol%. ● Answer the following: ● Effluct Reactor Cooling & Water Separator ● The H2 Product stream is essentially pure hydrogen but only 90% of the hydrogen in the Cooled Syn Gas is recovered as product. The remaining hydrogen is recovered in the Tail Gas stream. Free Water Cooled Syll Gus H2 H2O CO2 CO C1 Total PSA How much hydrogen is produced in H2 Product [in kmol/hr]? How much free water is produced after the initial cooling step [in kmol/hr]? What is the composition of the Tail Gas stream [in mol%]? Tail Gas Effluent Component mol% 55.9 26.1 13.9 0.1 4.0 100.0 H₂ Product
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