The pKa of phenol is 10.0 and the pKa of para-nitrophenol is 7.2. Given this information, one knows that The conjugate base of para-nitrophenol must be less stable than the conjugate base of phenol The conjugate acid of para-nitrophenol must be more stable than the conjugate base of phenol The conjugate base of para-nitrophenol must be more stable than the conjugate base of phenol Both acids are bases

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter20: Acidity And Pka Of Phenols
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The pKa of phenol is 10.0 and the pKa of para-nitrophenol is 7.2. Given this information, one knows that
The conjugate base of para-nitrophenol must be less stable than the conjugate base of phenol
The conjugate acid of para-nitrophenol must be more stable than the conjugate base of phenol
The conjugate base of para-nitrophenol must be more stable than the conjugate base of phenol
Both acids are bases
Transcribed Image Text:The pKa of phenol is 10.0 and the pKa of para-nitrophenol is 7.2. Given this information, one knows that The conjugate base of para-nitrophenol must be less stable than the conjugate base of phenol The conjugate acid of para-nitrophenol must be more stable than the conjugate base of phenol The conjugate base of para-nitrophenol must be more stable than the conjugate base of phenol Both acids are bases
Consider the following reaction at equilibrium.
NH3 + H₂O <-> NH4+ + OH
What would happen to the equilibrium if the hydroxide was removed as fast as it was
produced?
the rate of formation of ammonia would decrease
the rate of formation of ammonia would increase
the rate of formation of hydroxide would stay the same
removing of the hydroxide is not possible as it violates the second law of
thermodynamics
Transcribed Image Text:Consider the following reaction at equilibrium. NH3 + H₂O <-> NH4+ + OH What would happen to the equilibrium if the hydroxide was removed as fast as it was produced? the rate of formation of ammonia would decrease the rate of formation of ammonia would increase the rate of formation of hydroxide would stay the same removing of the hydroxide is not possible as it violates the second law of thermodynamics
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