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The oxygen in water is primarily (99.8%) 16O, but water enriched with the heavy isotope 18O is also available. When a ketone or aldehyde is dissolved in H2O, the isotopic label becomes incorporated into the carbonyl group: R2CPO  H2O n R2CPO  H2O. Explain.

The oxygen in water is primarily (99.8%) 16O, but water enriched with the heavy isotope 18O is also available. When a ketone or aldehyde is dissolved in H2O, the isotopic label becomes incorporated into the carbonyl group: R2CPO  H2O n R2CPO  H2O. Explain.

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter10: Alcohols
Section: Chapter Questions
Problem 10.52P: Alcohols are important for organic synthesis, especially in situations involving alkenes. The...
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The oxygen in water is primarily (99.8%) 16O, but water enriched with the
heavy isotope 18O is also available. When a ketone or aldehyde is dissolved in
H2O, the isotopic label becomes incorporated into the carbonyl group: R2CPO
 H2O n R2CPO  H2O. Explain.

 

 

The oxygen in water is primarily (99.8%) 160, but water enriched with the heavy isotope 18O is also available. When a ketone or aldehyde is dissolved in H20, the isotopic label becomes incorporated into the carbonyl group: R2C=0 + H20 → R2C=0 + H20. Explain| Problem 9.12
Transcribed Image Text:The oxygen in water is primarily (99.8%) 160, but water enriched with the heavy isotope 18O is also available. When a ketone or aldehyde is dissolved in H20, the isotopic label becomes incorporated into the carbonyl group: R2C=0 + H20 → R2C=0 + H20. Explain| Problem 9.12
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