The mechanism proposed for the oxidation of iodide ion by the hypochlorite ion is shown below. Step 1 Step 2 CIO + H₂O I + HCIO HIO + OH HCIO + OH → HIO + CI (fast, equilibrium) This is reversible Step 3 IO + H₂O (fast) This is not reversible a. What is the overall reaction for this mechanism? Answer within the test and not on scratch paper. b. What are the intermediates if any are present? Answer within the test and not on scratch paper. c. What is the rate law expression for each step of the mechanism (including any reversible steps)? Answer this question on your scratch paper, clearly labeled. d. What is the predicted rate law expression for this reaction? Show all work to receive any credit. Answer this on your scratch paper, clearly labeled e. What would be the expected units for k using seconds for the time unit? Answer within the test and not on the scratch paper. (slow) This is not reversible

The mechanism proposed for the oxidation of iodide ion by the hypochlorite ion is shown below. Step 1 Step 2 CIO + H₂O I + HCIO HIO + OH HCIO + OH → HIO + CI (fast, equilibrium) This is reversible Step 3 IO + H₂O (fast) This is not reversible a. What is the overall reaction for this mechanism? Answer within the test and not on scratch paper. b. What are the intermediates if any are present? Answer within the test and not on scratch paper. c. What is the rate law expression for each step of the mechanism (including any reversible steps)? Answer this question on your scratch paper, clearly labeled. d. What is the predicted rate law expression for this reaction? Show all work to receive any credit. Answer this on your scratch paper, clearly labeled e. What would be the expected units for k using seconds for the time unit? Answer within the test and not on the scratch paper. (slow) This is not reversible

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions

Section: Chapter Questions

Problem 84GQ

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