The decalinols A and B can be equilibrated using aluminum isopropoxide in 2-propanol (isopropyl alcohol) containing a small amount of acetone. Al[OCH(CH,),1, НО acetone ОН A B Assuming a value of AG° (equatorial to axial) for cyclohexanol is 4.0 kJ (0.95 kcal)/mol, calculate the percent of each decalinol in the equilibrium mixture at 25°C.
The decalinols A and B can be equilibrated using aluminum isopropoxide in 2-propanol (isopropyl alcohol) containing a small amount of acetone. Al[OCH(CH,),1, НО acetone ОН A B Assuming a value of AG° (equatorial to axial) for cyclohexanol is 4.0 kJ (0.95 kcal)/mol, calculate the percent of each decalinol in the equilibrium mixture at 25°C.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.18P: If the G for a reaction is 4.5 kcal/mol at 298 K, what is the Keq for this reaction? What is the...
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