Suppose the reaction between nitric oxide and oxygen proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + O2(9) – NO2(g) + O(g) 2 NO(g) + O(g) –→ NO2(g) Suppose also k, «k,. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k|| Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k-2 for k = the reverse of the two elementary reactions in the mechanism.
Suppose the reaction between nitric oxide and oxygen proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + O2(9) – NO2(g) + O(g) 2 NO(g) + O(g) –→ NO2(g) Suppose also k, «k,. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k|| Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k-2 for k = the reverse of the two elementary reactions in the mechanism.
Chapter17: Spontaneity, Entropy, And Free Energy
Section: Chapter Questions
Problem 23Q: Monochloroethane (C2H5Cl) can be produced by the direct reaction of ethane gas (C2H6) with chlorine...
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