Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter19: Transitition Metals, Coordination Chemistry And Metallurgy
Section: Chapter Questions
Problem 19.4QE
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State, with justification, whether you expect nitric oxide (NO) to be a stronger or weaker pi-acceptor ligand than CO?
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Can you summary between your 2 previous answers which one is correct?
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"The π* orbital of NO is partially filled with an unpaired electron, which makes it less efficient in accepting electron density from the metal’s d orbitals. On the other hand, the fully empty pi*orbital of CO can strongly overlap with the metal’s d orbitals, resulting in a stronger π-back bonding interaction and a stronger metal-ligand bond. " Is this correct and makes NO weaker?
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