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Since CO2 makes up 0.0355% of the atmosphere (on the average) calculate the molar fraction of [CO2•H2O] in the unpolluted rain water

Since CO2 makes up 0.0355% of the atmosphere (on the average) calculate the molar fraction of [CO2•H2O] in the unpolluted rain water

Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter13: Fundamental Equilibrium Concepts
Section: Chapter Questions
Problem 12E: Show that the complete chemical equation, the total ionic equation, and the net ionic equation for...
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Since CO2 makes up 0.0355% of the atmosphere (on the average) calculate the molar fraction of [CO2•H2O] in the unpolluted rain water (please use constants in table attached)
Selected Henry's Law Constants and Equilibrium Constants at 298 K. К (М) H (mole L-1 atm-1) Equilibrium H20 → H* + OH- 1.0 x 10-14 CO2 + H20 → CO2·H2O 3.4 x 10-2 CO2·H20 > H* + HCO3 4.3 x 10-7 HCO3 > H* + CO32- 4.7 x 10-11 SO2 + H20 > SO2·H2O SO2·H2O H* + HSO3" 1.23 1.32 x 102 HSO3 H* + SO3²- 6.42 х 108 NH3 + H20 > NH3'H2O 62 NH3 H2O NH4* + OH 1.8 x 105 HNO3 + H20 €→ HNO3-H20 2.1 x 105 HNO3·H2O → H* + NO3 15.4 H2O2 + H20 → H2O2·H2O H2O2·H2O → H* + HO2 O3 + H20 → O3·H2O 7.45 x 104 2.5 x 10-12 0.011
Transcribed Image Text:Selected Henry's Law Constants and Equilibrium Constants at 298 K. К (М) H (mole L-1 atm-1) Equilibrium H20 → H* + OH- 1.0 x 10-14 CO2 + H20 → CO2·H2O 3.4 x 10-2 CO2·H20 > H* + HCO3 4.3 x 10-7 HCO3 > H* + CO32- 4.7 x 10-11 SO2 + H20 > SO2·H2O SO2·H2O H* + HSO3" 1.23 1.32 x 102 HSO3 H* + SO3²- 6.42 х 108 NH3 + H20 > NH3'H2O 62 NH3 H2O NH4* + OH 1.8 x 105 HNO3 + H20 €→ HNO3-H20 2.1 x 105 HNO3·H2O → H* + NO3 15.4 H2O2 + H20 → H2O2·H2O H2O2·H2O → H* + HO2 O3 + H20 → O3·H2O 7.45 x 104 2.5 x 10-12 0.011
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