Scott prepares a solution which contains a large excess of iron and a small amount of thiocyanate. He notices a faint orange color appear in the solution once mixed. He repeats this process with a higher concentration of thiocyanate and notices a deepening of the orange color in the solution once mixed. Explain what has happened to the equilibrium in this case. Has the value of Keq changed? Explain.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
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Scott prepares a solution which contains a large excess of iron and a small amount of thiocyanate. He notices a faint orange color appear in the solution once mixed. He repeats this process with a higher concentration of thiocyanate and notices a deepening of the orange color in the solution once mixed. Explain what has happened to the equilibrium in this case. Has the value of Keq changed? Explain.

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