Release HCI has a strong catalytic influence on the dehydrochlorination of PVC according to: * -Chain transfer mechanism -lonic-molecular mechanism O -Free radical mechanism
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- 1.What is ceiling temperature in thermodynamics of polymerization? Explain the correlation of ceiling temperature with polymers. Show the equations to support your answer. 2.What is floor temperature in thermodynamics of polymerization? Explain the correlation of floor temperature with polymers. Show the equations to support your answer. 3.Discuss the differences between ceiling temperature and floor temperature.Expalin that- A tri-bi functional monomer system gels at about 83% conversion during polymerization.نقطة واحدة نقطة واحدة نقطة واحدة = ||| - ۹:۱۲ Almost all thermoset are .38 ...............moulded by A. injection moulding. B. Comerssion. C. Blow moulding. The hybridization of carbon .39 .atom in benzene is A 20+ 2 T. B - 40 C-10+ 2. .Bond angle in acetylene is - 40 A - 120⁰ B - 180⁰ C - 109⁰ A K O B
- Addition (chain-growth) polymerization reactions often terminate by combination or disproportionation. However, there is another class of deactivation reactions, called chain transfer reactions, which are usually relevant to the final degree of polymerization (dp). How might you expect the dp of a polymerization reaction deactivated by chain transfer compare/contrast with polymerizations terminated by combination or disproportionation?POLYMER CHEMISTRY - 1. Briefly describe what is thermoplastic, thermoset plastic and elastomer. Give examples to clarify your answers. 2. Briefly discuss the effect of thermodynamic on polymerization. 3. What are important factors influencing the properties of polymers?Polyethylene terephthalate is an example of synthetic material in Materials and Engineering. 1. Describe the relation of its building blocks in connection to its “bulk” (materials) properties. (No need for essay, just a brief scientific explaination!) If you may, please send link as well of the reference that you use for the answer).
- Thermoresponsive polymers: In detail describe the chemical principles of thermal response (why are they thermoresponsive?).Q.2: Discus the kinetics of addition polymerization reaction.State whether it is possible to determine whether one polymer is more likely to crystallize than the other. If it is possible, note which is the more likely and then cite reason(s) for your choice. If it is not possible to decide, state why. a) Linear and syndiotactic poly(vinyl chloride); linear and isotactic polystyrene b) Network phenol-formaldehyde; linear and heavily crosslinked cis-isoprene c) Linear polyethylene; lightly branched isotactic polypropylene d) Alternating poly(styrene-ethylene) copolymer; random poly(vinyl chloridetetrafluoroethylene) copolymer wwaw m
- Which of the following statement/s is/are true for the polymerization mechanisms? I. In both condensation and addition polymerization, the same mechanism operates throughout polymerization. II. In addition polymerization polymerization is necessarily initiated using initiator, but it is not necessary in condensation polymerization. II. In condensation polymerization all monomers are rapidly consumed at the early stage of the reaction, but some monomer remains even at long reaction time in addition polymerization. IV. In both condensation and addition polymerization, average molecular weight increases with increasing reaction time. A I and II B Il and II III and IV D II, II and IVFrom the practical standpoint, is it better to use a "good" solvent or a "poor" solvent when measuring polymer molecular weight? Explain.Which of the following statement/s is/are true for free radicalic polymerization? I. It involves three fundamental steps: initiation, propagation, and termination. II. Initiation of free radical polymerization is brought about by the addition of small quantities of compounds called initiators. III. Sometimes a fourth step called chain transfer may be involved. IV. In termination, the initiated monomer described above adds other monomers – usually thousands of monomer molecules – in rapid succession. I, Il and IV A B II, II and IV I, Il and III I, Il and IV