[References] Nitryl chloride, NO2CI, decomposes into nitrogen dioxide and chloride. 2NO, Cl(g) → 2NO2 (g) + Cl2 (9) A proposed mechanism is NO,Cl NO2 + Cl (slow) NO, Cl + Cl → NO, + Cl2 (fast) Write the rate law predicted by this mechanism.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.77QE
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[References]
Nitryl chloride, NO, Cl, decomposes into nitrogen dioxide and chloride.
2NO2CI(g)
+ 2NO2 (9) + Cl2 (g)
A proposed mechanism is
NO, Cl → NO, + Cl (slow)
NO, Cl + Cl → NO2 + Cl, (fast)
Write the rate law predicted by this mechanism.
(Use k for the rate constant.)
Rate =
Transcribed Image Text:[References] Nitryl chloride, NO, Cl, decomposes into nitrogen dioxide and chloride. 2NO2CI(g) + 2NO2 (9) + Cl2 (g) A proposed mechanism is NO, Cl → NO, + Cl (slow) NO, Cl + Cl → NO2 + Cl, (fast) Write the rate law predicted by this mechanism. (Use k for the rate constant.) Rate =
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