Reaction Substrate Reagents Products Bromination Br2 dioxane, 0 °C HNO3 acetic anhydride Nitration CH;C(O)CI benzene, SnCl4 Friedel-Crafts acylation

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter2: Polar Covalent Bonds; Acids And Bases
Section2.9: Predicting Acid–base Reactions From Pka Values
Problem 14P
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Exercise 41. Draw the structures of the products formed by the following reactions.
Reaction
Substrate
Reagents
Products
Bromination
Br2
dioxane, 0 °C
Nitration
HNO3
acetic anhydride
Friedel-Crafts acylation
CH3C(O)CI
benzene, SnCl4
SO3, H2SO4
H9SO4, 220 °C
Sulfonation
HNO3
NaNO3, 370 °C
Nitration
Transcribed Image Text:Exercise 41. Draw the structures of the products formed by the following reactions. Reaction Substrate Reagents Products Bromination Br2 dioxane, 0 °C Nitration HNO3 acetic anhydride Friedel-Crafts acylation CH3C(O)CI benzene, SnCl4 SO3, H2SO4 H9SO4, 220 °C Sulfonation HNO3 NaNO3, 370 °C Nitration
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