Rank the following complexes from smallest to largest d-orbital splittingi) [Fe(CN)613-ii) [Fe(CN)614-iii) [FeCl6]4-iv) [Ru(CN)6]3-Oiv < ii < i < iiiiii < ii < i < ivOiv < i < i < iiiOiii < i < iv < iiOi < iii < ii < iv

The complexes given are (i) [Fe(CN)6]3−, (ii) [Fe(CN)6]4−, (iii) [Fe(Cl)6]4−, (iv) [Ru(CN)6]3−

Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]3- ii) [Fe(CN)614- iii) [FeCl6]4- iv) [Ru(CN)6]3- Oiv < ii < i < iii Oiii < i < i < iv Oiv < i < i < iii Oiii < i < iv < ii Oi < iii < ii < iv

Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]3- ii) [Fe(CN)614- iii) [FeCl6]4- iv) [Ru(CN)6]3- Oiv < ii < i < iii Oiii < i < i < iv Oiv < i < i < iii Oiii < i < iv < ii Oi < iii < ii < iv

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.30QAP

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Question

Rank the following complexes from smallest to largest d-orbital splitting
i) [Fe(CN)613-
ii) [Fe(CN)614-
iii) [FeCl6]4-
iv) [Ru(CN)6]3-
Oiv < ii < i < iii
iii < ii < i < iv
Oiv < i < i < iii
Oiii < i < iv < ii
Oi < iii < ii < iv

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