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Rank in order of Increasing Bronsted acidity the structures I, II and III.

Rank in order of Increasing Bronsted acidity the structures I, II and III.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Rank in order of Increasing Bronsted acidity the structures I, II and III. 

(D) Rank in order of Increasing Bronsted acidity the structures I, II and III. CF3 OH OH Cl3C CC|3 OH A. I<II < III B. I< III < || C. II < | < III III D. II<III<I In I and III the negative charge is delocalized directly onto the carbons that carry the electron withdrawing substituents, the electronegative elements lower the energy of the electrons via the inductive effect, which is stronger for more electronegative F compared to Cl. In II the negative charge is never on the carbon with the substituents, the conjugate base from II thus has the highest energy electrons and B is the weakest acid
Transcribed Image Text:(D) Rank in order of Increasing Bronsted acidity the structures I, II and III. CF3 OH OH Cl3C CC|3 OH A. I<II < III B. I< III < || C. II < | < III III D. II<III<I In I and III the negative charge is delocalized directly onto the carbons that carry the electron withdrawing substituents, the electronegative elements lower the energy of the electrons via the inductive effect, which is stronger for more electronegative F compared to Cl. In II the negative charge is never on the carbon with the substituents, the conjugate base from II thus has the highest energy electrons and B is the weakest acid
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