Q7. Fill in the missing intermediates, products and reagents in the reaction scheme shown below. 1. BaHg, THF 1. KMnO,. KOH (aq) 2. H,Oz. NaOH 2 HCI (an) Compound A Compound B conc. HPO, 1. PhMgBr CH,N, 2. HCI in H,0 heat Compound C Compound D 1. BHe. THF 1. NaH 2. H,O, NaOH 2. Compound C Compound E Compound F Compound G

Chemistry & Chemical Reactivity
9th Edition
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter3: Chemical Reactions
Section: Chapter Questions
Problem 87SCQ: Most naturally occurring acids are weak acids. Lactic acid is one example....
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Q7. Fill in the missing intermediates, products and reagents in the reaction scheme shown below.
1. KMnO. KOH (aq)
2 HCI (an)
1. BaHe, THF
2. H,Oz. NaOH
Compound A
Compound B
conc. H,PO,
1. PhMgBr
CH,N,
2. HCl in H,0
heat
Compound C
Compound D
1. BHe. THF
1. NaH
2. H;O,. NaOH
2. Compound C
Compound E
Compound F
Compound G
Q8. Provide a plausible mechanism that leads to the major product of the reaction scheme shown below.
1. SOCI,
HO,
2. NH(CH)2
Q9. Provide a plausible mechanism that leads to the major product of the reaction scheme shown below.
1. PBr3. Cl2
он
2. H,0
Q10. Provide the starting material needed to create the below product using m-chloroperbenzoic acid as
the active reagent. Then draw the mechanism that facilitates this transformation.
Transcribed Image Text:Q7. Fill in the missing intermediates, products and reagents in the reaction scheme shown below. 1. KMnO. KOH (aq) 2 HCI (an) 1. BaHe, THF 2. H,Oz. NaOH Compound A Compound B conc. H,PO, 1. PhMgBr CH,N, 2. HCl in H,0 heat Compound C Compound D 1. BHe. THF 1. NaH 2. H;O,. NaOH 2. Compound C Compound E Compound F Compound G Q8. Provide a plausible mechanism that leads to the major product of the reaction scheme shown below. 1. SOCI, HO, 2. NH(CH)2 Q9. Provide a plausible mechanism that leads to the major product of the reaction scheme shown below. 1. PBr3. Cl2 он 2. H,0 Q10. Provide the starting material needed to create the below product using m-chloroperbenzoic acid as the active reagent. Then draw the mechanism that facilitates this transformation.
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