Q2: Nitramide decomposes in water according to the chemical equation, kobs 0,N-NH, The observed rate law is the following, The proposed mechanism is: k₁ O,N-NH, k3 N₂0 + H₂O d[N₂0] dt =kobs O_N-NH + N₂0 [0zN – NH2] [H+] H* 0,N-NH H* + OH H₂O Fast Is the reaction mechanism consistent with the observed rate law? If so, what is the relationship between kobs and the rate constants of the individual steps? Fast Equilibrium OH Slow
Q2: Nitramide decomposes in water according to the chemical equation, kobs 0,N-NH, The observed rate law is the following, The proposed mechanism is: k₁ O,N-NH, k3 N₂0 + H₂O d[N₂0] dt =kobs O_N-NH + N₂0 [0zN – NH2] [H+] H* 0,N-NH H* + OH H₂O Fast Is the reaction mechanism consistent with the observed rate law? If so, what is the relationship between kobs and the rate constants of the individual steps? Fast Equilibrium OH Slow
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
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