Problem 9 3458 6-H 3000 IR Spectrum 4000 znrl=3 300 2000 1600 1200 B00 v (cm') 100 Mass Spectrum Ho Gh 80 60 Mare blanch M 118 1SI No significant Uv 40 absorption above 220 nm 20- 103 CeH1402 40 80 120 160 200 240 280 m/e 13C NMR Spectrum (100 O MH CDCI, solution) =14-14 =zaro DEPT CH CH, CHt proton decoupled solvent 200 160 120 80 40 8 (ppm) H NMR Spectrum (200 MHz. CDCI, solution) Exchanges with D20 TMS 6. 8. 5. 1. 98 wad ase 10

Problem 9 3458 6-H 3000 IR Spectrum 4000 znrl=3 300 2000 1600 1200 B00 v (cm') 100 Mass Spectrum Ho Gh 80 60 Mare blanch M 118 1SI No significant Uv 40 absorption above 220 nm 20- 103 CeH1402 40 80 120 160 200 240 280 m/e 13C NMR Spectrum (100 O MH CDCI, solution) =14-14 =zaro DEPT CH CH, CHt proton decoupled solvent 200 160 120 80 40 8 (ppm) H NMR Spectrum (200 MHz. CDCI, solution) Exchanges with D20 TMS 6. 8. 5. 1. 98 wad ase 10

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter9: Atomic Absorption And Atomic Fluorescence Spectrometry

Section: Chapter Questions

Problem 9.16QAP

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Resolves into 13C NMR Spectrum (50.0 MHz, CDCI, solution) two signals at higher field DEPT CgH11Br Resolves into two signals at higher field expansions proton decoupled solvent 35.0 34.0 ppm 200 160 120 80 40 O 8 (ppm) 1H NMR Spectrum (200 MHz, CDCI, solution) expansion 3.0 2.5 ppm TMS 10 9 8 7 6 5 4 3 2 1 8 (ppm) Determine the structure of the compound based on the above information
43 184 IR Spectrum (Iquid film) 4000 3000 100 80 60 40 20 40 13C NMR Spectrum (100.0 MHz, CDCI, solution) 9 80 DEPT CH₂ CH₂4 CHA proton decoupled 200 ¹H NMR Spectrum (400 MHz CDCI, solution) expansion 7.5 7.3 ppm 8 P 10 SAMSUNG Galaxy A53 5G 2000 1600 V (cm) 105 M+- 134 120 160 m/e 160 09b0f2ca-eac1-4... 1200 T L 120 2.8 2.7 ppm 7 6 ww 800 Mass Spectrum C10H14 200 240 280 T 1 5 solvent " 80 expansions 1.8 1.7 ppm 1 4 3:54 م 0 *1 470 صفحة Problem 96 UV Spectrum max 260 nm (log10=2.5) PE 40 1.45 1.35 ppm 3 2 Problem 97 08 (ppm) expansion 1.05 0.95 TMS I 0 8 (ppm) 1 202 تمشح بـ 100 جيجابايت تخزين على OneDrive cloud لمدة 6 أشهر 185.
опанит 1715 1600 IR Spectrum 100 4000 (liquid film) 43 80 75 60 M 40 20 % of base peak 10 3000 40 C 13C NMR Spectrum (20.0 MHz, CDCI solution) proton decoupled 9 80 200 ¹H NMR Spectrum (100 MHz, CDCI, solution) 101 8 2000 v (cm¹) M** 132 120 160 m/e 160 7 6 1200 120 Mass Spectrum 200 240 280 800 C-H 5 C6H1203 solvent L 80 4 -CH3 No significant UV absorption above 220 nm 3 H-C-H u -CH3 40 2 59 TMS 0 1 8 (ppm) TMS 0 8 (ppm)
Unrounded Rounded ε∗,L/μmolε∗,L/μmol 0.0259825 0.0260 heres data: TZ # Concentration Absorbance at 430 nmnm 1 33.6480 0.931 2 25.2360 0.757 3 16.8420 0.210 4 8.41200 0.137 5 4.20600 0.122
4000 IR Spectrum quid film) 100 80 60 40 YI 2248 41 10 3000 43 40 proton decoupled "C NMR Spectrum (150 MHz CDC, solution) 68 DEPT CH, CH, 1 CHT 9 200 ¹H NMR Spectrum (600 MHz, CDC, solution) M83 (<1%) 80 120 2000 v (cm) 8 m/e 160 160 2.3 L 7 1600 2.2 200 ryper 1200 6 ▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬▬ 120 Mass Spectrum 240 21 2.0 expansions (not to scale) 800 I CsH₂N 280 5 expansion 80 4 270 255 256 255 expansion No significant UV absorption above 220 nm 27.0 245 250 255 1.0 3 40 L 2 0 8 (ppm) 1 1 TMS L 1 0 8 (ppm) 10 ¹H-¹C me-HSQC Spectrum (600 MHz, CDC, solution) Black cross-peaks CH and CH Red cross-peaks CH₂ ppm 20 ¹H-"C HMBC Spectrum (600 MHz, CDC), solution) -22 -24 -26 -28 116 118 120 122 124 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0.6 ppm ppm 20 22 -24 26 28 -116 118 -120 122 -124 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0.6 ppm IR: List bands and possible/probable structural units responsible Band (cm³) Possible…
4000 100 80 60 20 % of base peak 3376 40 10 3000 59 13C NMR Spectrum (50.0 MHz, CDCI, solution) 173 proton decoupled 200 I 9 80 ¹H NMR Spectrum (200 MHz, CDCI, solution) DEPT CH₂ CH₂ CH4 IR Spectrum (liquid film) 2000 M+88 (<1%) 120 1600 v (cm¹) m/e 160 160 I I 8 7 mmm 1 120 200 240 6 1200 . Mass Spectrum L 800 1 5 C5H₁20 280 solvent L 80 4 problem 78 3 No significant UV absorption above 220 nm 40 Il 08 (ppm) 1 2 1 TMS 0 8 (ppm)
7.) From the following sets of data, please propose a reasonable structure for the unknown organic compound. This molecule is entirely composed of C, H, and N only. Please show all of your work and feel free to write on the spectra any clues as to the structure. 4000 3000 2000 1000 S DO Infrared spectrum of unknown. KBr salt plate sample. 100 MS-NU-6396 80 60 40 20 - 10 20 30 40 50 60 70 80 90 100 110 m/z Mass spectrum of unknown. Molecular ion = 83.1 Relative Intensity
4000 100 80 60 IR Spectrum (liquid film) 40 20 $ 2 2960 3000 41 77 79 40 13C NMR Spectrum (50.0 MHz. CDCI, solution) proton decoupled 200 ¹H NMR Spectrum (200 MHz, CDCI, solution) T 40 10 9 80 2000 107/109 1 8 120 v (cm¹) m/e 1600 M** 156/158/160 160 160 3.5 1200 120 200 240 766 800 Mass Spectrum expansions ppm 2.5 1 7 6 5 650 C3H6Br Cl 280 T 2.0 ppm solvent 80 4 H-C-H Problem 18 No significant UV absorption above 220 nm H-C-H 1 3 40 H-C-H 0 1 2 1 124 8 (ppm) TMS 0 8 (ppm) 107
Concentration of FeSCN2+ Absorbance (Y axis) Percent Transmittance (%T) (X axis) 100 1.00E-04 0.495 32 2.00E-04 0.955 11.1 3.00E-04 1.398 Calibration Curve (Absorbance vs. Concentration of FESCN²*) 1.6 1.4 y = 4713.6x. 1.2 1 0.8 0.6 0.4 0.2 0.00005 0.0001 0.00015 0.0002 0.00025 0.0003 0.00035 Concentration of FeSCN²+ Absorbance
[X] (ppm) 0.00 10.0 15.0 20.0 25.0 30.0 35.0 x-axis Resources UV-Vis absorbance data for molecule X collected at 425 nm using a 3.50 cm cuvet is given in the table. [X] (M) 0.00 1.00 × 10 4 1.50 × 10-4 2.00 × 10-4 2.50 × 10-4 3.00 x 10-4 3.50 x 10-4 O %T %T T A 100.0 1.000 0.000 49.4 0.494 0.306 34.9 0.349 0.457 25.3 0.253 0.597 17.3 0.173 0.761 15.4 0.154 0.813 13.9 0.139 0.857 Prepare a plot using the linear range of the data to determine the molar absorptivity. What should be plotted on each axis to determine the molar absorptivity of molecule X at this wavelength? x Give Up? y-axis Hint OT 8:1
13C NMR Analysis of Aspirin Chemical Shift (Observed ppm) Assignment(s) (A'-J') Expected Chemical Shift Range (ppm) B' D' E' JOH Acetylsalicylic Acid (Aspirin) 169 & 170 152 125 135 (4 peaks) - 122 20 160 140 120 100 Figure 14.13 125.7-MHz 13C-NMR spectrum of aspirin in CDCl3. solvent 80 60 40 20 ppm
Compund AFK has a maximum absorbance of 650 nm. Its molar absorptivity at 650 is 8400 M−1cm−1 and the path length is 1 cm. Using a spectrophotometer, determine the concentration of Compound AFK it is absorbance at 650 nm is 0.700 ? 8.33x10-5 mol/L 1.20 x104 mol/L 1.08 x10-3 mol/L 7.74 x10-2 mol/L