Predict the major product for the following Diels-Alder reaction. Clearly indicate the stereochemistry if there any.

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Problem Set 9
CHM 3150 Organic Chemistry II
Name:
Topics covered: Kinetic vs. thermodynamic control of diene additions, Diels-Alder reaction
Predict the major product for the following Diels-Alder reaction. Clearly indicate
the stereochemistry if there any.
1
a.
b.
C.
d.
CH,0.
CH;OCH,
O,N
H.
Which diene and dienophile would react to give the following Diels-Alder
přoduct?
OCH
3.
Provide the major product of the below reaction. Identify the product if 1,2-
addtion product (KIN Pdt) or 1,4-addtion product (TD pdt).
HBr
-78 °C
Briefly explain why 1.2 product of the above reaction is kinetically favored (KIN Pdt)?
Transcribed Image Text:Chemistry Hi I need some help with my homework, thank you for your help! Problem Set 9 CHM 3150 Organic Chemistry II Name: Topics covered: Kinetic vs. thermodynamic control of diene additions, Diels-Alder reaction Predict the major product for the following Diels-Alder reaction. Clearly indicate the stereochemistry if there any. 1 a. b. C. d. CH,0. CH;OCH, O,N H. Which diene and dienophile would react to give the following Diels-Alder přoduct? OCH 3. Provide the major product of the below reaction. Identify the product if 1,2- addtion product (KIN Pdt) or 1,4-addtion product (TD pdt). HBr -78 °C Briefly explain why 1.2 product of the above reaction is kinetically favored (KIN Pdt)?
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