Pls help ASAP on both.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter10: Oxidation And Reduction
Section: Chapter Questions
Problem 10CTQ
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Pls help ASAP on both. 

Why do you need three equivalents of base in the synthesis of a terminal alkyne
from a suitable dihalide?
This is incorrect, only two equivalents of base are required
Jy
Without the third equivalent of base the mechanism would be SN1 and not an
elimination
The full reaction would not go to completion otherwise
All dihalides always require excess base for the synthesis of all alkynes
Terminal alkynes cannot be synthesized from dihalides
Transcribed Image Text:Why do you need three equivalents of base in the synthesis of a terminal alkyne from a suitable dihalide? This is incorrect, only two equivalents of base are required Jy Without the third equivalent of base the mechanism would be SN1 and not an elimination The full reaction would not go to completion otherwise All dihalides always require excess base for the synthesis of all alkynes Terminal alkynes cannot be synthesized from dihalides
What is the expected major product for the following reaction sequence?
ONV
OV
OH
+ enantiomer
+ enantiomer
11
1. BD, THF
2. H₂O₂, NaOH
OH D
+ enantiomer
OH
+ enantiomer
IV
+ enantiomer
V
Transcribed Image Text:What is the expected major product for the following reaction sequence? ONV OV OH + enantiomer + enantiomer 11 1. BD, THF 2. H₂O₂, NaOH OH D + enantiomer OH + enantiomer IV + enantiomer V
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