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- Predit ds produc 1. Br ght 2.1-BuOK 38 Which represet soy depis 2mthyleyclohexeol where the wo ubatitum are S.BH, in THE 4 HO, NaOH (A) (m) CH (A) 1014 (B) BH CH OH (C) (D) (9 O он (D) 25. What radical interediate is fonmed in CHa this reaction? CH HC 2 HOOH H,C 30 Which molecules sre chiral? H. hv HO (m) COH Br (C) HO (D) HO V 26. Predict the product OH SOci II IV (A) 1,II, II, & IV (C) H& II pyridine (B) II, II, A IV (D) I1& IV (A) (B) CI 31. Explain why this synthetic route will not produce this product. şoCi 1) CHMgr 2) HHP (C) (D) SOCI H,HO heal Which reagents produce this transformation? 27. (A) The Grigrard reagent will not add to the ketone. OH HO. (B) The Grignard reagent will not add to the alcohol. (A) 1) LIAIH 2) H, H;0 (C) The Markovnikov rule will lead to a different product. (B) NABH,, HO (D) Acid catalyzed dehydration will lead to the formation of the more (C) PCC, CH,Cl; (D) KMNO, NaOH, H;O, heat thermodynamically stable alkene. What is the formal charge of oxygen in…S Imidaz0le concider Nonaromatic ntiaromatic oc an Aomatic compand HNBr -OCCCH3)3 а. b. -OCH,CH3 CI CI C. -NH2 (2 equiv)
- Homewock (1) When a sample ol 4-heplanone WAS Iradiiled ili 150 = with 1 radiation wath 4 power outpul of 60 W under condria of t absorplion, il w as lound that 3 8 tinial C;L wir md Whte quantum yield for the formalion of etlhen0NH₂ 1) Acetone/ -H₂0 2) CH₂(CO₂Et), NaOCH; O A B. C. D EtO₂C. C) N -CO₂Et -CO₂Et B) CO₂Et CO₂Et CO₂Et NH…CH个 个 U ← 1. (CH3)2CHMgBr 2. Neutralizing work-up Select to Draw 1 V Q 1. CH3CCNa 2. H3O+ Select to Draw Ma
- QUESTION 3 Predict the IR absorption bands (peaks) observed in the spectrum of 3-methylcyclohexanone. sp3 C-H stretching (-2850-2960 cm 1) sp2 C-H stretching (-3000-3100 cm-1) Alcohol O-H stretch (-3300 cm-1, broad) C-O double bond stretch (-1700 cm-1) Aromatic out of plane bend for monosubstitution (690-710 and 730-770 cm-1). Aromatic out of plane bend for para (1,4) disubstitution (810-840 cm-1). Aromatic out of plane bend for meta (1,3) disubstitution (690-750 and 750-810 cm 1). Aldehyde C-H stretch (2750 and 2850 cm-1). Carboxylic acid (carboxy group) O-H stretch (-2500-3000 cm-1, broad) N-H stretch (2 bands at -3400 cm-1) N-H bend (-1600 cm*1) Aromatic C-C double bond stretches (-1500 and 1600 cm-1). Aromatic overtones (1667-2000 cm-1) O O O OR; = 0.70 R = 0.55 R; = 0.47 -+------ Eluent: EtOAc OH ОН OH 1 2 3 5. Which compound corresponds to Rf = 0.70? O Standards are needed for reference. 1 3What is the name of the following compound +1 Br Brill.. |||| OH₂ OH₂ Co Br H₂O OH₂ trans-teraaquadibromocobalt(1) bromide trans-teraaquadibromocobaltate(1) bromide Ocis-teraaquadibromocobalt(1) bromide cis-teraaquadibromocobaltate(1) bromide