One of the reactions that occurs in polluted air in urban areas is 2NO2(g) + O3(g) –→N2O5(g) + O2(g). Assume that a species with the formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate = k[NO2][O3]. Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(g) + O3(g) – NO3(g) + O2(g) (fast) NO3(g) + NO2(g) → N2O5(g) (slow) NO2(g) + O3(g) – NO3(g) + O2(g) (fast) 4NO3(g) 2N2O5(g) + O2(g) (slow) NO2(g) + O3(g) –→ NO3(g) + O2(g) (slow) NO3(g) + NO2(g) → N2O5(g) (fast) NO2(3) + O3(g) → NO3(g) + O2(g) (slow) 4NO3(3) → 2N20O5(g) + O2(g) (fast)
One of the reactions that occurs in polluted air in urban areas is 2NO2(g) + O3(g) –→N2O5(g) + O2(g). Assume that a species with the formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate = k[NO2][O3]. Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(g) + O3(g) – NO3(g) + O2(g) (fast) NO3(g) + NO2(g) → N2O5(g) (slow) NO2(g) + O3(g) – NO3(g) + O2(g) (fast) 4NO3(g) 2N2O5(g) + O2(g) (slow) NO2(g) + O3(g) –→ NO3(g) + O2(g) (slow) NO3(g) + NO2(g) → N2O5(g) (fast) NO2(3) + O3(g) → NO3(g) + O2(g) (slow) 4NO3(3) → 2N20O5(g) + O2(g) (fast)
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.10PSP: The Raschig reaction produces the industrially important reducing agent hydrazine, N2H4, from...
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![One of the reactions that occurs in polluted air in urban areas is 2NO2(g) + O3(g) –→N2O5(g) + O2(g). Assume that a species with the
formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate = k[NO2][O3].
Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law.
NO2(g) + O3(g) – NO3(g) + O2(g) (fast)
NO3(g) + NO2(g) → N2O5(g) (slow)
NO2(g) + O3(g) – NO3(g) + O2(g) (fast)
4NO3(g)
2N2O5(g) + O2(g) (slow)
NO2(g) + O3(g) –→ NO3(g) + O2(g) (slow)
NO3(g) + NO2(g) → N2O5(g) (fast)
NO2(3) + O3(g) → NO3(g) + O2(g) (slow)
4NO3(3) → 2N20O5(g) + O2(g) (fast)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F34784e04-15c4-48e3-8d00-89b2475118ca%2Fbd461517-6377-4934-b8ab-71b67192340b%2F7jkk96o_processed.png&w=3840&q=75)
Transcribed Image Text:One of the reactions that occurs in polluted air in urban areas is 2NO2(g) + O3(g) –→N2O5(g) + O2(g). Assume that a species with the
formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate = k[NO2][O3].
Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law.
NO2(g) + O3(g) – NO3(g) + O2(g) (fast)
NO3(g) + NO2(g) → N2O5(g) (slow)
NO2(g) + O3(g) – NO3(g) + O2(g) (fast)
4NO3(g)
2N2O5(g) + O2(g) (slow)
NO2(g) + O3(g) –→ NO3(g) + O2(g) (slow)
NO3(g) + NO2(g) → N2O5(g) (fast)
NO2(3) + O3(g) → NO3(g) + O2(g) (slow)
4NO3(3) → 2N20O5(g) + O2(g) (fast)
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