( do e f g h ) On the basis of the 18-electron rule, identify the first-rowtransition metal for each of the following:a. [M(CO);]+b. H;CM(CO)sc. M(CO),(CS)(PPh;)Brd. [(7-C,H)(7°-C;H3)M(CO)]OCH3(OC),M=C`C¢H5е.f. [(n-C,H4)(n°-CsH3)M]*g. (7°-C,H3(n°-C;H3)M(CH;)(NO) (has linearly coor-dinated NO)h. [M(CO),I(diphos)]¯(diphos = 1,2-bis(diphenylphosphino)ethane)

We have to find the 3d metal persent in the complexes to form 18 e system

On the basis of the 18-electron rule, identify the first-row transition metal for each of the following: a. [M(CO),]+ b. H;CM(CO)s c. M(CO),(CS)(PPh;)Br d. [(7-C,H;(7°-CgH;)M(CO)] OCH, (OC);M=C `C,H5 е. f. [(n-CgHq)(n°-CgH3)M]* g. (7-C,H3X7-CgH;)M(CH)(NO) (has linearly coor- dinated NO) h. [M(CO),I(diphos)]¯ (diphos = 1,2-bis(diphenylphosphino)ethane) %3D

On the basis of the 18-electron rule, identify the first-row transition metal for each of the following: a. [M(CO),]+ b. H;CM(CO)s c. M(CO),(CS)(PPh;)Br d. [(7-C,H;(7°-CgH;)M(CO)] OCH, (OC);M=C `C,H5 е. f. [(n-CgHq)(n°-CgH3)M]* g. (7-C,H3X7-CgH;)M(CH)(NO) (has linearly coor- dinated NO) h. [M(CO),I(diphos)]¯ (diphos = 1,2-bis(diphenylphosphino)ethane) %3D

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.15QAP

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