On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kJ/mol for tert-butyl, and 2.3 kJ/mol for bromine. Calculate the ratio of the two observed products at 28.0 °C using the following equation: AG-RT In Keq The gas constant, R, is 8.314 J/K-mol. (Enter your answer to two significant figures.) Ratio: Major to 1 Minor

On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kJ/mol for tert-butyl, and 2.3 kJ/mol for bromine. Calculate the ratio of the two observed products at 28.0 °C using the following equation: AG-RT In Keq The gas constant, R, is 8.314 J/K-mol. (Enter your answer to two significant figures.) Ratio: Major to 1 Minor

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter2: Alkanes And Cycloalkanes

Section: Chapter Questions

Problem 2.45P: Gibbs free energy differences between axial-substituted and equatorial-substituted chair...

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On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kl/mol for tert-butyl, and 2.3 k/mol for bromine. Calculate the ratio of the two observed products at 48.0 "C using the following equation: AG --RT In Ka The gas constant, R, is 8.314 J/K-mol. (Enter your answer to two significant figures.) Ratio: to 1 Major Minor
On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kJ/mol for tert-butyl, and 2.3 kJ/mol for bromine. Calculate the ratio of the two observed products at 46.0 °C using the following equation: AG-RT In Keq The gas constant, R, is 8.314 J/K.mol. (Enter your answer to two significant figures.) Ratio: Major to 1 Minor
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