Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.92QE
Related questions
Question
Recall from Section 1.10B that there is restricted rotation around carbon–carbon double bonds. Maleic acid and fumaric acid are two isomers with vastly different physical properties and pKa values for loss of both protons. Explain why each of these differences occurs.
![OH
HO-
но
-OH
maleic acid
130
fumaric acid
mp (°C)
solubility (g/L) in H2O at 25 °C
pКaт
pKa2
286
788
1.9
3.0
4.5
6.5](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F201db226-3f17-4a25-a23c-0bca87bbe202%2F7bb29f85-17ff-43fc-abd5-e34ea924668d%2Flwbrofo.png&w=3840&q=75)
Transcribed Image Text:OH
HO-
но
-OH
maleic acid
130
fumaric acid
mp (°C)
solubility (g/L) in H2O at 25 °C
pКaт
pKa2
286
788
1.9
3.0
4.5
6.5
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