OH CO₂H + NH₂ SO3H 1. Give the mechanism for the reaction 2. Discuss the reason(s) why the dye molecule you synthesized is the specific color it is 3. After dying, which fabric gives the deepest color in your case? Why might different fabrics dye differently? 4.Discuss the advantages of combinatorial synthesis.
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- 2. As you are probably aware, some proteins "glow," most famously Green Fluorescent Protein (2008 Nobel Prize in Chemistry). The color of these proteins can be shifted by an elimination reaction as described in the article "The E1 Mechanism in Photo-Induced B-Elimination Reactions for Green-to-Red Conversion of Fluorescent Proteins." NRVF. NRVF. His-Nu H N-ATTL. KİKGRX ATTL. HO NH HO His-Ce hv His-CB a) Propose a simple mechanism for the reaction using arrow pushing. b) How might His-Na (which sits in the surrounding protein) accelerate the reaction? To initiate the reaction, should this histidine be in its acid or conjugate base form? Draw this form of histidine side chain. c) How about His-CB? d) Provide a brief explanation of why the reaction yields a shift from green to red color.Organic chemistry 2 :write the complete mechanism for the formation of benzalacetone .I analyze the reaction of Compound C with excess NaOH at 298 K. and get the following results for its absorbance over time: Time Absorbance (no units) 0.5087 (seconds) 10 0.3746 20 0.3155 30 0.2333 40 0.2011 50 0.1778 60 0.1602 Using these results, along with a spreadsheet, answer the following question: What is the pseudo-rate constant for the reaction of compound C with NAOH at 298 K? Select one: a. 2.602 1/s b. 0.6455 1/s c. 0.07414 1/s d. 0.3217 1/s e. 7.371 1/s
- What are the final products for these reactions? *mechanisms not necessary6 of 6 14. For the following first-order reaction X Y, the number of X molecules are placed in three same vessels at 100°C (i = 8 molecules, ii = 6 molecules, iii = 12 molecules) (a) compare rates of the reaction in these three vessels? (b) if the volume of each vessels were doubled, how would the relative rates be changed? (c) Explain the comparative t/2 of the reactions in (i) to (iii)? 15. Variation of the rate constant with temperature for the first-order reaction 2N2OS(g)→2N2O4ag) + Ozg) is given in the following table. Dctermine graphically the activation cnergy for the reaction. k (s) 1.74 x 105 T (K) 295 6.61 x 10 2.51 x 104 305 315 7.59 x 104 2.40 x 103 325 335ΚΗ Consider the following reaction which has the observed kinetic isotope effect = 1.5. kD Cy2 "PH Δ Cy2 -PI...pt + -P Cy2 Cy2 A) Draw a mechanism for this reaction and identify the type of reaction which is occurring.
- In unpolluted air at 300 K, the hydroxyl radical OH reacts with CO with a bimolecular rate constant of 1.6 × 101' L mol-1 s-1 and with CH4 with a rate constant of 3.8 × 10° L mol¬1 s-1. Take the partial pressure of CO in air to be constant at 1.0 × 10-7 atm and that of CH4 to be 1.7 x 10-6 atm, and assume that these are the primary mecha- nisms by which OH is consumed in the atmosphere. Cal- culate the half-life of OH under these conditions.Can you show the mechanism (arrows) of the last "decomposition" step with water, ROH, and heat?write the mechanism for the following reactions Br Br₂ CH2Cl2 MCBPA Å -Br