Ø 5.) Predict the major product: Br BIX CH₂OH heat Which mechanism is most likely: S2, S1, E2,ED Explain your choice: 3° Carbon, weak base, but he applied Provide the curved arrow mechanism to form the major product: - C CH₂OH X - DIM Br This reaction also produces a significant amount of a minor product. Draw its structure and circle the mechanism that forms the minor product: SN2, SN1, E2, E1
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- 5. a) When the molecule below is treated with HCI, the product distribution shown is obtained. Use curved arrow formalism to draw a mechanism for this process. Account for the product distribution and draw resonance structures for the intermediate that leads to the major product. The m HCI CI + s 1o(29nil no awa eib ys leldwsio (2tniog 01).E (15 % CI2 tw ledsl< 1% lad olualom 85 %(4d) and PhMgBr, followed by reaction with the acid. Please draw that mechanism here! Even though benzoic acid is reformed as the product, a reaction does take place between benzoic acid 1. PhMgBr HO, 2. H30*For each reaction, draw the complete mechanism and the major organic product(s), paying attention to stereochemistry. (a) (b) OH LOH (еxcess) ? ? CH,Cl2 CH2CI2
- 2. Provide a mechanism and the favored product(s) with the following reaction. Remember MeOH всион MeOHShow the El mechanism for the following reaction, which includes a rearrangement. Use your work to predict the product as well. OH Conc. H2SO4Predict the product(s) and provide the complete mechanism for each reaction below.
- Draw the mechanism and predict the major product for each of the following reactions. (a) (b) 1. NaH 1. NaH -? ? 2. Br I 2.Identify the major product of the following reaction sequence. 1) [H*], H₂NNH2, (-H₂O) 2) KOH/H₂O, heat HO₂C HO₂C HO CO,H OH OH There is no reaction under these conditions or the correct product is not listed here.N(CH2CH3)3 + HNO3 --------> a.) rewrite the reaction using bond-line structure of reagents and products of the reaction b.) supply the curved arrows explaining the mechanism of the reaction
- 4. For the following, a) predict the product and b) using curved arrows to show electron movement, provide a reasonable mechanism for each reaction. CI CH3OH ??? (-HCI) CI H2N (-HCI) + ??? NH2Consider the elimination reaction shown below: Me- H2SO4 Ме— он Me alkene-containing product(s) heat, – H2O i) By providing a curly arrow mechanism, identify the two distinct alkene-containing products. ii) Identify the major product and explain why it is the major product.5. Draw the major and minor products of the following reaction. (H3C),CCH,CH3 H2SO4 heat он