Nitrogen dioxide reacts bimolecularly in the gas phase to give NO2 + NO2 + ----> NO +NO + O2. The temperature dependence of the second-order rate constant for the rate law d[P]/dt = k[NO2]2 is given below. What are the Values of the steric factor P and the reactive cross-section for the reaction? Take σ = 0.60 nm2. T / K 600 700 800 1000 k / (cm3 mol−1 s−1) 4.6 ✕ 102 9.7 ✕ 103 1.3 ✕ 105 3.1 ✕ 106
Nitrogen dioxide reacts bimolecularly in the gas phase to give NO2 + NO2 + ----> NO +NO + O2. The temperature dependence of the second-order rate constant for the rate law d[P]/dt = k[NO2]2 is given below. What are the Values of the steric factor P and the reactive cross-section for the reaction? Take σ = 0.60 nm2. T / K 600 700 800 1000 k / (cm3 mol−1 s−1) 4.6 ✕ 102 9.7 ✕ 103 1.3 ✕ 105 3.1 ✕ 106
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.38E: List at least four experimentally determined parameters that you, an experimenter, can define when...
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Nitrogen dioxide reacts bimolecularly in the gas phase to give
NO2 + NO2 + ----> NO +NO + O2.
The temperature dependence of the second-order rate constant for the rate law d[P]/dt = k[NO2]2 is given below. What are the Values of the steric factor P and the reactive cross-section for the reaction? Take σ = 0.60 nm2.
T / K | 600 | 700 | 800 | 1000 |
---|---|---|---|---|
k / (cm3 mol−1 s−1) | 4.6 ✕ 102 | 9.7 ✕ 103 | 1.3 ✕ 105 | 3.1 ✕ 106 |
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