needed for this question. In the laboratory a "coffee cup" calorimeter, or constant pressure calorimeter, is frequently used to determine the specific heat of a solid, or to measure the energy of a solution phase reaction. A student heats 65.89 grams of tin to 98.22 °C and then drops it into a cup containing 79.41 grams of water at 20.89 °C. She measures the final temperature to be 23.93 °C. The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.54 3/°C. Assuming that no heat is lost to the surroundings calculate the specific heat of tin. t Specific Heat (Sn) = J/g°C. ot Winer- Metal- sample Thermometer Stirri trod

needed for this question. In the laboratory a "coffee cup" calorimeter, or constant pressure calorimeter, is frequently used to determine the specific heat of a solid, or to measure the energy of a solution phase reaction. A student heats 65.89 grams of tin to 98.22 °C and then drops it into a cup containing 79.41 grams of water at 20.89 °C. She measures the final temperature to be 23.93 °C. The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.54 3/°C. Assuming that no heat is lost to the surroundings calculate the specific heat of tin. t Specific Heat (Sn) = J/g°C. ot Winer- Metal- sample Thermometer Stirri trod

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter6: Thermochemistry

Section: Chapter Questions

Problem 112AE: In a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each...

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Enthalpy a A 100.-g sample of water is placed in an insulated container and allowed to come to room temperature at 21C. To heat the water sample to 41C, how much heat must you add to it? b Consider the hypothetical reaction,2X(aq)+Y(l)X2Y(aq)being run in an insulated container that contains 100. g of solution. If the temperature of the solution changes from 21C to 31C, how much heat does the chemical reaction produce? How does this answer compare with that in part a? (You can assume that this solution is so dilute that it has the same heat capacity as pure water.) c If you wanted the temperature of 100. g of this solution to increase from 21C to 51C, how much heat would you have to add to it? (Try to answer this question without using a formula.) d If you had added 0.02 mol of X and 0.01 mol of Y to form the solution in part b, how many moles of X and Y would you need to bring about the temperature change described in part c. e Judging on the basis of your answers so far, what is the enthalpy of the reaction 2X(aq) + Y(l) X2Y(aq)?
A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.
Hydrogen is an ideal fuel in many respects; for example, the product of its combustion, water, is nonpolluting. The heat given off in burning hydrogen to gaseous water is 5.16 104 Btu per pound. What is this heat energy in joules per gram? (1 Btu = 252 cal; see also Table 1.4.)
Water gas, a mixture of carbon monoxide and hydrogen, is produced by treating carbon (in the form of coke or coal) with steam at high temperatures. (See Study Question 83.) C(s) + H2O(g) CO(g) + H2(g) Not all of the carbon available is converted to water gas since some is burned to provide the heat for the endothermic reaction of carbon and water. What mass of carbon must be burned (to CO2 gas) to provide the energy to convert 1.00 kg of carbon to water gas?
A piece of iron was heated to 95.4C and dropped into a constant-pressure calorimeter containing 284 g of water at 32.2C. The final temperature of the water and iron was 51.9C. Assuming that the calorimeter itself absorbs a negligible amount of heat, what was the mass (in grams) of the piece of iron? The specific heat of iron is 0.449 J/(gC), and the specific heat of water is 4.18 J/(gC).
In a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each experiment. Since the amount of water is not constant from experiment to experiment, the mass of water must be measured in each case. The heat capacity of the calorimeter is broken down into two parts: the water and the calorimeter components. If a calorimeter contains 1.00 kg water and has a total heat capacity of 10.84 kJ/C, what is the heat capacity of the calorimeter components?
When one mole of ethylene gas, C2H4, reacts with fluorine gas, hydrogen fluoride and carbon tetrafluoride gases are formed and 2496.7 kJ of heat are given off. What is Hf for CF4(g)?
Classify each process as exothermic or endothermic. (a) ice melts (b) gasoline burns (c) steam condenses (d) reactants products, H = 50 kJ
Hypothetical elements A2 and B2 react according to the following equation, forming the compound AB. A2(aq)+B2(aq)2AB(aq);H=+271kJ/mol If solutions A2(aq) and B2(aq), starting at the same temperature, are mixed in a coffee-cup calorimeter, the reaction that occurs is a exothermic, and the temperature of the resulting solution rises. b endothermic, and the temperature of the resulting solution rises. c endothermic, and the temperature of the resulting solution falls. d exothermic, and the temperature of the resulting solution falls. e exothermic or endothermic, depending on the original and final temperatures.
Chlorine dioxide, ClO2, is a reddish yellow gas used in bleaching paper pulp. The average speed of a ClO2 molecule at 25C is 306 m/s. What is the kinetic energy (in joules) of a ClO2 molecule moving at this speed?
In a calorimetric experiment, 6.48 g of lithium hydroxide, LiOH, was dissolved in water. The temperature of the calorimeter rose from 25.00C to 36.66C. What is H for the solution process? LiOH(s)Li(aq)+OH(aq) The heat capacity of the calorimeter and its contents is 547 J/C.
How much heat is required to raise the temperature of 100. grams of water from 25C near room temperature to 100.C its boiling point? The specific heat of water is approximately 4.2Jperg-K. a.3.2104J b.32J c.4.2104J d.76J

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