MeO2C Li -N(allyl)2 MeO NH3 - ELOH Br Pd(PPH3)4, Cul

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions
Section21.SE: Something Extra
Problem 34MP: Predict the product(s) and provide the complete mechanism for each reaction below.
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b) Give the expected major product of each of the following reactions or
sequences of reactions.
Reaction mechanisms are not required, but may receive partial credit if
the given main product is incorrect. Ensure that you circle the major
product structure if you choose to give a reaction mechanism.
i)
MeO2C
Li
-N(allyl)2
MeO-
NH3
- ELOH
Br
Pd(PPH3)4, Cul
СНО
EtzN, THF, RT, 0.5 h
ОН
Transcribed Image Text:b) Give the expected major product of each of the following reactions or sequences of reactions. Reaction mechanisms are not required, but may receive partial credit if the given main product is incorrect. Ensure that you circle the major product structure if you choose to give a reaction mechanism. i) MeO2C Li -N(allyl)2 MeO- NH3 - ELOH Br Pd(PPH3)4, Cul СНО EtzN, THF, RT, 0.5 h ОН
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