me proposed mechanism for the formation of phosgene (COC12) can be written in a simplified form as: Cl₂(g) Part A What rate law corresponds to this mechanism? k₁ k5 [CO]³/2 [C1₂] k3 K₁ K₂ k5 O k5 Oks k4 k₂ k3 k₁ k3 K₁ K₂ k¹ [CO][C1₂]³/2 [CO][C1₂]³/2 k₁ k₂ k3 k1 [CO]³/2 [C1₂] 2C1(g) Cl(g) + CO(g) COCI(g) k4 COCI(g) + Cl₂(g) → COC12 (g) + Cl(g) ks k₂ Fast Fast Slow

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
he proposed mechanism for the formation of phosgene (COC12) can be written in a simplified form as:
Cl₂ (g)
Part A
What rate law corresponds to this mechanism?
k3
k5 [CO]3/2 [C1₂]
k4
kı
k₂
2 [CO][C1₂13/2
kı
OK √
K3K¹ [CO][Cl₂13/2
K₁ K₂
KS TOV F
K2CO³/2 [C1₂]
kı
Cl(g) + CO(g)
COCI(g) + Cl₂ (g)
2
k4
→
ks
2Cl(g)
COCI(g)
COC1₂(g) + Cl(g)
Fast
Fast
Slow
Transcribed Image Text:he proposed mechanism for the formation of phosgene (COC12) can be written in a simplified form as: Cl₂ (g) Part A What rate law corresponds to this mechanism? k3 k5 [CO]3/2 [C1₂] k4 kı k₂ 2 [CO][C1₂13/2 kı OK √ K3K¹ [CO][Cl₂13/2 K₁ K₂ KS TOV F K2CO³/2 [C1₂] kı Cl(g) + CO(g) COCI(g) + Cl₂ (g) 2 k4 → ks 2Cl(g) COCI(g) COC1₂(g) + Cl(g) Fast Fast Slow
Expert Solution
steps

Step by step

Solved in 3 steps with 4 images

Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The