lon selective electrode (ISE) is an electrochemical device for the selective determination of the concentration/activity of an ion based on the principle of potentiometry. Typical examples include pH electrodes and the fluoride ISE. To use an ISE, the potential of the ISE is first measured with a range of solutions containing different concentrations of the analyte. Then, a calibration curve is constructed by plotting the potential versus log₁0[ion]. For an ideal Ca²+ ion selective electrode, which of the following slopes is the one that you would expect? (T = 25 °C) Select one: O a. -30 mV/dec O b. 30 mV/dec O c. 59 mV/dec O d. -59 mV/dec

Chemistry: An Atoms First Approach
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Chapter17: Electrochemistry
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Problem 147CP: The measurement of pH using a glass electrode obeys the Nernst equation. The typical response of a...
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lon selective electrode (ISE) is an electrochemical device for
the selective determination of the concentration/activity of
an ion based on the principle of potentiometry. Typical
examples include pH electrodes and the fluoride ISE. To use
an ISE, the potential of the ISE is first measured with a range
of solutions containing different concentrations of the
analyte. Then, a calibration curve is constructed by plotting
the potential versus log₁0[ion]. For an ideal Ca²+ ion selective
electrode, which of the following slopes is the one that you
would expect? (T = 25 °C)
Select one:
a. -30 mV/dec
O b.
O c.
30 mV/dec
59 mV/dec
O d. -59 mV/dec
Transcribed Image Text:lon selective electrode (ISE) is an electrochemical device for the selective determination of the concentration/activity of an ion based on the principle of potentiometry. Typical examples include pH electrodes and the fluoride ISE. To use an ISE, the potential of the ISE is first measured with a range of solutions containing different concentrations of the analyte. Then, a calibration curve is constructed by plotting the potential versus log₁0[ion]. For an ideal Ca²+ ion selective electrode, which of the following slopes is the one that you would expect? (T = 25 °C) Select one: a. -30 mV/dec O b. O c. 30 mV/dec 59 mV/dec O d. -59 mV/dec
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