Let operator Ĥ. Let be one of the normalized eigenfunctions of a Hamiltonian be an approximation of . What conditions must be satisfied by V, so that is necessarily satisfied. (V|ĤI V) ≤ (ÿ ĤIV)
Let operator Ĥ. Let be one of the normalized eigenfunctions of a Hamiltonian be an approximation of . What conditions must be satisfied by V, so that is necessarily satisfied. (V|ĤI V) ≤ (ÿ ĤIV)
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter11: Quantum Mechanics: Model Systems And The Hydrogen Atom
Section: Chapter Questions
Problem 11.17E
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![Let be one of the normalized eigenfunctions of a Hamiltonian
operator H. Let V be an approximation of . What conditions must be
satisfied by V, so that
is necessarily satisfied.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe280ddcf-e51d-4991-ba07-1d22583ec788%2F02de0710-354f-4f7f-8e34-2e3b780e9280%2Fopob4j_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Let be one of the normalized eigenfunctions of a Hamiltonian
operator H. Let V be an approximation of . What conditions must be
satisfied by V, so that
is necessarily satisfied.
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