KOCCCH)3 Hg(OAc)2, H20 followed by NaBHA/OH"

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
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Question 17
How will you convert 2-propanol, CH3CH(OH)CH3 to 1-propanol, (CH3CH2CH2OH) ?
O 1) KOC(CH3)3
2) Hg(OAc)2, H20 followed by NaBH4/OH
O 1) H2SO4, heat
2) BH3 followed by H2O2/OH
O 1) H2SO4. heat
2) Hg(OAc)z, H2O followed by NaBH/OH
O 1) KOC(CH3)3
2) H20/H*
O 1) KOC(CH)3
2) BH3 followed by H2O2/OH
Question 20
When 1-methylcyclohexene is treated with BH3.THF followed by H2O2/OH, it leads
to:
O addition of water according to Markovnikov's rule (Anti Addition of water)
addition of water according to Anti-Markovnikov's rule (Syn Addition of water)
O addition of water according to Anti-Markovnikov's rule (Anti Addition of water)
addition of water according to Markovnikov's rule (Syn Addition of water)
Question 21
Transcribed Image Text:Question 17 How will you convert 2-propanol, CH3CH(OH)CH3 to 1-propanol, (CH3CH2CH2OH) ? O 1) KOC(CH3)3 2) Hg(OAc)2, H20 followed by NaBH4/OH O 1) H2SO4, heat 2) BH3 followed by H2O2/OH O 1) H2SO4. heat 2) Hg(OAc)z, H2O followed by NaBH/OH O 1) KOC(CH3)3 2) H20/H* O 1) KOC(CH)3 2) BH3 followed by H2O2/OH Question 20 When 1-methylcyclohexene is treated with BH3.THF followed by H2O2/OH, it leads to: O addition of water according to Markovnikov's rule (Anti Addition of water) addition of water according to Anti-Markovnikov's rule (Syn Addition of water) O addition of water according to Anti-Markovnikov's rule (Anti Addition of water) addition of water according to Markovnikov's rule (Syn Addition of water) Question 21
Question 14
When 2-methylpent-2-ene is reacted with BH3 followed by H2O2/OH", the major
product obtained will be
O HOCH2CH(CH3)CH2CH2CH3
O (CH32C(OH)CH2CH2CH3
O (CH3)2CHCH(OH)CH2CH3
O (CH3)2CHCH2CH(OH)CH3
Transcribed Image Text:Question 14 When 2-methylpent-2-ene is reacted with BH3 followed by H2O2/OH", the major product obtained will be O HOCH2CH(CH3)CH2CH2CH3 O (CH32C(OH)CH2CH2CH3 O (CH3)2CHCH(OH)CH2CH3 O (CH3)2CHCH2CH(OH)CH3
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