In CrBr2, which crystallizes with a distorted CdI2 structure, four Cr-Br distances are 254 pm and two are 300 pm. Explain the origin of the different Cr-Br bond lengths in this extended ionic or network covalent solid.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
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In CrBr2, which crystallizes with a distorted CdI2 structure, four Cr-Br distances are 254 pm and two are 300 pm. Explain the origin of the different Cr-Br bond lengths in this extended ionic or network covalent solid.

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