II. Predict the products of the ff: elimination reactions and show the mechanisms involv HO H2SO4 (a) (b) CH3CO2N CH3CO,H (c) CH3 OH H2SO4 -CH3
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- 4 Which of the following alcohols could not be made selectively by hydroboration-oxidation of an alkene? Explain. about the (b) (a) (c) OH | CH3CH₂CH₂CHCH3 In H OH (CH3)2CHC(CH3)2 (d) CH3 vino zbiory 1 OH o no atou OH vollot edt evig H noituloa siblos V H но но CHO SHO=3₂HƆ m² CH3s 10 out of ST bewollot giaylonoso no WBTⱭ 12-8 His to edustrie 5 wode, $2-8 OnMX dilw osviel vitabII. Predict the products of the ff: elimination reactions and show the mechanisms involve. (a) HO H2SO4 (b) CI CH3CO2N. CH3CO2H (c) CH3 HO- H2SO4 CH3(c) Write a mechanism to account for the products of the following reactions: CH3 CH, H3C. H3C. -H,0 OH -CH3 H,SO, H;C CH3
- Provide the products for the reactions shown below. Suggest a reasonable mechanism (show electron flow or provide a brief explanation) to account for each step, paying attention to stereochemical details. (a) OBn 1. EtO)2CO, NaOEt 2. H* 3. H₂O*, heat 1. NaH, THF 2. Br, THFChemistry 3. Provide reagents/conditions to accomplish the following syntheses. Several steps are required in some cases. (c) (d) H2N. NH2 но H. NH2 но9. Plan syntheses of the following compounds. You may use the given starting material and any compound containing three or fewer carbons. (a) OH (b) Br Br- (c) ✓ -OTS (d) OH
- ep by step using arrows pushing) mechanisms that account fo the products of the following reaction (a) H₂N. Br H₂O HO H IN N.* Predict the products and stereochemistry for the following reduction reaction NaBH4 (a) EtOH H2 Lindlar catalyst (b) 3-Hexyne (c) 3-Hexyne (d) CEC H2 Ni₂B (P-2) Na NH3Predict the product(s) for each reaction below. In each case, draw the resonance forms of the intermediate to explain the observed regiochemistry. (a) (b) (c) (d) CN CH30. CH3 HNO3 H₂SO4 CH₂ (CH₂CHCI, AIC? Cl₂, FeCl3 ? B. CUC
- S.10. Describe the product formed as a result of the reaction between cyclohexanone and 3-butene-2-one by also writing the mechanism of the reaction. 1'CH,ON H;C, 2 HO CH,Draw structural formulas for the following the compounds: (d) cis-1,3-dicyclohexylcyclopentane (e) (Z)-2-cyclohexyl-4-methylhept-2-en-3-ol (f) 3-methoxybenzaldehydePredict the major products of the following reactions, including stereochemistry where appropriate. (a) cyclooctanol + NaOCl/HOAc (b) cyclopentylmethanol + CrO3 . pyridine . HCl