For each subsection, arrange the substituents in progressive order of priority based on the OCahn-Ingold-Prelog nomenclature. а) -ОН -OCH3 - COOH -CHO
Q: CI I HICIH I HICIH I HICIH HICIH I H b) I C-H HICIH HICIH 1-6-5 HICIH HICIH H HIC-C-H c) 91110 91110
A:
Q: What is the proper relationship of the substituents for the major product (only) of the following…
A: In the given structure amide group is present in the ring. We know amide group is ortho/ para…
Q: Organize these compounds in order of increasing_heat of hydrogenation (that is, list them from most…
A: Heat of hydrogenation is referred to the amount of energy released during the process of…
Q: Using Cahn-Ingold-Prelog rules, rank these substituents from highest priority to lowest priority. II…
A:
Q: Which reaction is not stereospecific? Br,/CCI, trans-2-butene Br,/H2O cis-2-pentene II HBr…
A:
Q: Arrange the following group in order of increasing priority. Q) -OCH3 -CH(CH3)2 -B(CH2CH3)2 -H
A: The CIP sequence rules are used to assign the R and S configuration. Rule 1: First, select the…
Q: What are all the likely alkene prodcuts in the reaction of trans-1,2-bromocyclohexane treated with…
A: In organic chemistry, inter conversion of organic molecule takes place from one form to another form…
Q: What is the structure of (15.2R)-1-ethyl-2-methyl-1,2-epoxycyclohexane %3D II IV
A: The R, and S configuration of a molecule can be determined on the basis of the Chan-Ingold-Prelog…
Q: В. Н.С C=C CH3 С. Н Н c=c CH,CH3 A. H;C CH3 H H H. H H
A: Higher is the stability of alkene, lower is the heat of hydrogenation. Heat of hydrogenation ∝…
Q: Rank the following alkenes in order of increasing stability: CH,=C(CH3)CH,CH3, CH2=CHCH(CH3)2, and…
A: Stability of alkene is directly proportional to number of hyperconjugation structures and number of…
Q: Rank each group of radicals in order of increasing stability. (CH3),ĊCH,CH(CH3)2 (CH),CHCHCH(CH,)2…
A: a.) Carbon radicals are electron deficient so they tend to get stabilized by any factor which…
Q: Arrange the substituents in order of decreasing priority when determining E/Z stereochemistry of an…
A: The substituents given are,
Q: CH CH-C-C C-CH- CH3 CH3 -CH3 + H2 CH3 Pt, Pd, or Ni B) UV CH + Cl2 C) CH CH-CH3 + HBr D) peroxides…
A:
Q: CH3 „CH3 B В Е A -E H3C" A I II What substituent is positioned at A on Structure l? O -H O -CH3 Q8.2…
A: The given change of a cyclohexane ring to a chair conformation is represented as follows:
Q: Rank the following groups in terms of their priority according to the Cahn-Ingold-Prelog system of…
A: According to the Cahn-Ingold-Prelog system, Priorities order of group depends upon atomic number of…
Q: To accomplish a Markovnikov addition of water to an unsymmetrical alkene, with minimal skeletal…
A:
Q: Br CH,0 CH3 CH;OH CHCH,CH3 Br
A: ->CH3O- is a base hence, there occur elimination reaction and anti periplanar beta hydrogen…
Q: Name each alkene and specify its configuration by the E,Z system
A: Name of the following compound : Identify the longest chain in the skeletal number it. Add the…
Q: i. 3-methyl-1-butene with HBr CH3 H,C=CH-ĆH-CH3 Major Product(s) of i. j. 2-methylbut-1-ene + Br2 in…
A: The major products obtained in each case have been described below.
Q: Name each alkene and specify its configuration by the E,Z system
A: In this question, first we will Identify the it is E/Z configuration and then give its name. You…
Q: Provide the IUPAC name for each of the following compounds. Pay close attention to stereochemistry.…
A: Introduction: IUPAC is the International Union of Pure and Applied Chemistry. It has set up the…
Q: Show how to accomplish the following conversion using reagents from the table. Br Br When only one…
A: To Solve this problem we have to complete the given reaction .
Q: 2. Please give the order of reactivity of alkenes CH3-C=ç-CH3 CH; CH3 CH3-C=CH-CH3 CH3-CH=CH-H CH3 B…
A: With the increase in the number of alkyl groups attached to the double bonded carbons, electron…
Q: 3. (S)-3-methoxy-2-methylpentan-2-ol
A:
Q: nyl-2-decacen-6-yne nyl-2-dodecen-6-yne nyl-10-decacen-6-yne nyl-10-dodecen-6-yne
A: The iupac nomenclature, first select the longest parent carbon chain which must include main…
Q: 4. In the following examples (where R represents the rest of the molecule), tell which is the best…
A: A leaving group is the one ,which departs with a pair of e- in heterolytic cleavage. A good leaving…
Q: What is the most proper name of the following ether? OCH3 a. (25,3R)-2-methoxy-3-methylpentane b.…
A: The IUPAC name of the following ether is
Q: Provide the correct set of reagents that would complete the following rxn? a) ) LAH, 2) HzO d) No,…
A: The reaction taking place is given as,
Q: 2.4 Rank each set of substituents in order of decreasing influence on electrophilic aromatic…
A: In electrophilic aromatic substitution the ease of reaction decreases with electron withdrawing…
Q: CH2(OH)-CH2-CH2-CH=CH-CH2-CH3 CH2=CH-CH2-CH2-CH=CH-CH2-CH3 H20 SN2 SN1 Addition FRH Elimination
A:
Q: Using the Cahn-Ingold-Prelog sequence rules, assign configurations to EACH of the alkenes (A-D) .as…
A: E–Z configuration is the method of describing the absolute stereochemistry of double bonds. To…
Q: 4,5-Disubstituted cyclopent-2-enones cyclopent-2-enones in basic solution. can rearrange to…
A:
Q: (S)-3-methyl-1-penten-4-yne; f. (3S,8S)-8-chloro-3,8-dimethyl-5-decyn-3-ol e. g.…
A: Structure of given compounds can be drawn by following IUPAC nomenclature rules.
Q: k. 3,3-dimethylpent-1-ene + catalytic amounts of H2SO4 in water CH3 H,C=CH- CH2-CH3 ČH3 Major…
A: The acid-catalyzed hydration of a double bond occurs through a carbocation intermediate. The…
Q: Part A CH,=CH `CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds),…
A:
Q: 1. Arrange each set in order of decreasing priority using (Cahn-Ingold-Prelog) priority rules…
A:
Q: Identify the substituent that would have the highest priority using Cahn-Prelog-Ingold rules. O…
A: CPI (CAHN-PRELOG-INHOLD) RULENJS ACCORDING TO THE MASS OF THE DIRECTLY BONDED ATOM.
Q: (b) 1-methyl -3-chloro-4-lodo Cyclo pentane (C) 1- Chloro-2-lodo-4-methyl Cyclo pentane (d)…
A: The question is based on concept of IUPAC NAMING of organic compounds. There are certain rules to…
Q: Considering both 5-methylcyclopenta-1,3-diene (A) and 7-methylcyclohepta-1,3,5-triene (B), which…
A: In case of A, if we remove the Hb+ than we will have a -ve charge on carbon which is in conjugation…
Q: Rank the following compounds in each group in order of increasing boiling point. 1. CH;CH,CH,l,…
A: Boiling point is the temperature at which the vapor pressure of a liquid is equal to the external…
Q: 2 mol H CHO -OH -OH H но +H H- -OH CH₂OH cyclization 'COOH PCI NaOCH₂ CH₂OH (8) (5) 1.) SOCI 2)…
A:
Q: Rank the following substituents in order of increasing activation strength: a. -N(CH3)2 b. -CN С.…
A:
Q: D D m) 3-hexyne to each of the folowing deuterated alkenes: CH;CH, CH, CH3 CH3 CH2 D and D CH, CH3…
A: Lindlar catalyst - It is heterogeneous catalyst that consist of pd deposited on calcium…
Q: 1 1-nonyne 1-chloro-4-iodobutane 2 1-decyne 5 1-chloro-5-iodopentane 1-tridecyne (C-13 alkyne) 6…
A:
Q: The expected Markovnikov addition product of HI to 2-methyl-2-butene A) B) C) D) E) 2-iodopentane…
A: Introduction: In addition reaction, the substituent get attach to the unsaturated compound without…
Q: Which substituent would be assigned the highest priority when naming an alkene E or Z? CH3 -C-H…
A: The correct option is given below:
Q: NH ? 6- ? 7- 8- 5.
A: A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two…
Please be clear in your writing
Step by step
Solved in 2 steps
- 1. Name compounds by IUPAC nomenclature CH₂CH-COOH a ОН 2) Find all of the heterofunctional compounds among following: ОН 2 сн, -ен, -с NH, OH COOH CH-OH CH,COOH e b COOH H-C-OH н-с- -ОН COOH -СООН f с H₂C-C-CH₂ 0 COOH HO-C-CH,COOH CH,COOH CH2-CH-CH2; OH ОН ОН g d ОН HOOC–C–CH,COOH ОН HOỌC –COOH б ONaGive the IUPAC name for each of the following: || CH,CH,-0-C-CH,CH, a. b. CH,CH,CH, СН,— С-О-CH,CH,CH,0 || CH,-O-C-(CH2)2 – CH3 O || CH-O - C - (CH2), – (CH = CH – CH2)2 – (CH2)3 – CH3 O || CH,- O-C-(CH2)8 – CH3 - 3 KOH
- ОН а) КН, 18C6 -CH,CH=CH2 CH3 80 °CGive the IUPAC name for each compound. Part 1 of 3 CH₂CH, H,C-C-CH_CH, CH, 1 H Part 2 of 3 X CH, H H,CCH,CH,-с-с-сH CH CH,CH, I H CH₂CH₂CH, Part 3 of 3 X H CH₂CH₂CH, H,CCH, -e-c-CH,CH, H,CCH, ЙThe reaction of CH -CH = CH - CH with HOH would form CH3 3. a) CH3 - CH CH - CH3 b) CH3 – C = C - CH3 с) О ОН Н ОН ОН // CНЗ-С-СНЗ d) CH3 - СH2-О-СН
- Provide an appropriate name for the following compound. 3-fluro u-methyl 5-chloro 7 OH CI F 5-chbro-3 fluro-4 methyl non-2-enol 2) Draw the molecule that corresponds to (3R,5R,6R)-5-cyclopropyl-6-ethyl-3-iodo-1-methylcyclohex-1-ene.Draw all of the products, both constitutional isomers and stereoisomers, of the following reactions. a) 4,4-dibromo-1-ethylcyclopentene ---->Br2,H2O b) 3,3-dibromo-1-ethylcyclopentene ----> HBr c) 3,3-dibromo-1,2-dimethylcyclopentene ----> 1. BH3. 2. H2O2, NaOH= highest priority group, 4 = lowest Rank the substituents shown below in order of Cahn-Ingold-Prelog priorities (1 priority group). -CH2BR -H -OH -CH3
- Explain the different products of the following two reactions by considering the mechanism by which each reaction proceeds. As part of your explanation, use the curved arrow formalism to draw a mechanism for each reaction. CH,OH CH2=CH-CH-CH, + Na*¯OCH, CH;=CH-CH-CH3 Br OCH, CH,=CH-CH-CH, + CH,OH – CH,=CH–CH–CH, + CH,CH=CHCH, Br OCH, OCH,FUNCTIONAL GROUP SUBSTITUENT NAME -X (F, CI, Br, I) halo- -OH hydroxy- -SH mercapto- -OR alkoxy- -NH2 amino- -CHO formyl or alkanoyl -C=0 Oxo-or keto- -COOH carboxy- Alkoxycarbonyl Halocarbonyl -COOR -COX -CN cyano- -CONH2 carbamoyl-C\ Rearrangement the following structures by increasing melting point? CH3 CH3 ÓH D\ Rearrangement the following structures by increasing boiling point? СООН CH3 NO2