For each reaction, calculate the value of the equilibrium constant (Keq) and the electrode potential of the system at the equivalence point (Eeq) of a hypothetical titration. Co³+ + Ti²+ Co²+ + Ti³+ E Co³+/Co²+ = 1.900 V ET¹+²+ = -0.370 V Keq = Eeq = V

Fundamentals Of Analytical Chemistry
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Chapter19: Applications Of Standard Electrode Potentials
Section: Chapter Questions
Problem 19.4QAP
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Question 4 of 23 >
For each reaction, calculate the value of the equilibrium constant (Keq) and the electrode potential of the system at the
equivalence point (Eeg) of a hypothetical titration.
Co³+ + Ti²+ Co²+ + Ti³+
E Co²+/Co²+ = 1.900 V
ET¹/T²+ = -0.370 V
Keq
=
Eeq =
V
Transcribed Image Text:Question 4 of 23 > For each reaction, calculate the value of the equilibrium constant (Keq) and the electrode potential of the system at the equivalence point (Eeg) of a hypothetical titration. Co³+ + Ti²+ Co²+ + Ti³+ E Co²+/Co²+ = 1.900 V ET¹/T²+ = -0.370 V Keq = Eeq = V
Question 4 of 23 >
Select the indicator that can be used to signal the end point of the hypothetical titration. Shown in parenthesis is the
reduction potential and the number of electrons transferred in the oxidation or reduction of the indicator.
O phenosafranine (E = +0.28 V, n = 1)
diphenylamine (Ein = +0.76 V, n = 2)
O 2,3'-diphenylamine dicarboxylic acid (En = +1.12 V, n = 2)
O indigo tetrasulfonate (Ein = +0.36 V, n = 2)
O diphenylamine sulfonic acid (E = +0.85 V, n = 2)
Omethylene blue (Ein = +0.53 V, n = 2)
O erioglaucin A (EIn = +0.98 V, n = 2)
Keq
2 Cut + SeO2 + 4H+ 2 Cu²+ + H₂SO3 + H₂O
E Cu²+/Cut = 0.150 V
E Seo /H₂SeO,
=
Eeq =
= 1.200 V
(assume the H+ concentration is 0.055 M)
V
Transcribed Image Text:Question 4 of 23 > Select the indicator that can be used to signal the end point of the hypothetical titration. Shown in parenthesis is the reduction potential and the number of electrons transferred in the oxidation or reduction of the indicator. O phenosafranine (E = +0.28 V, n = 1) diphenylamine (Ein = +0.76 V, n = 2) O 2,3'-diphenylamine dicarboxylic acid (En = +1.12 V, n = 2) O indigo tetrasulfonate (Ein = +0.36 V, n = 2) O diphenylamine sulfonic acid (E = +0.85 V, n = 2) Omethylene blue (Ein = +0.53 V, n = 2) O erioglaucin A (EIn = +0.98 V, n = 2) Keq 2 Cut + SeO2 + 4H+ 2 Cu²+ + H₂SO3 + H₂O E Cu²+/Cut = 0.150 V E Seo /H₂SeO, = Eeq = = 1.200 V (assume the H+ concentration is 0.055 M) V
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